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Curium(III) oxide is a compound composed of curium and oxygen with the chemical formula Cm 2 O 3. It is a crystalline solid with a unit cell that contains two curium atoms and three oxygen atoms. The simplest synthesis equation involves the reaction of curium(III) metal with O 2−: 2 Cm 3+ + 3 O 2−---> Cm 2 O 3. [1]
Metallic curium is annealed in air or in an oxygen atmosphere: [1] Cm + O 2 → CmO 2. Curium(III) hydroxide and curium(III) oxalate are also usually used for this purpose: Cm(OH) 4 → CmO 2 + 2H 2 O Cm(C 2 O 4) 2 → CmO 2 + 2CO 2 + 2CO. Another way is the reaction of curium(III) oxide in an oxygen atmosphere at 650 °C: [2] 2Cm 2 O 3 + O 2 ...
Curium readily reacts with oxygen forming mostly Cm 2 O 3 and CmO 2 oxides, [1] but the divalent oxide CmO is also known. [2] Black CmO 2 can be obtained by burning curium oxalate (Cm 2 (C 2 O 4) 3), nitrate (Cm(NO 3) 3), or hydroxide in pure oxygen. [3] [4] Upon heating to 600–650 °C in vacuum (about 0.01 Pa), it transforms into the whitish ...
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Figure 6:Reaction Coordinate Diagrams showing reactions with 0, 1 and 2 intermediates: The double-headed arrow shows the first, second and third step in each reaction coordinate diagram. In all three of these reactions the first step is the slow step because the activation energy from the reactants to the transition state is the highest.
The Ellingham diagram plots the Gibbs free energy change (ΔG) for each oxidation reaction as a function of temperature. For comparison of different reactions, all values of ΔG refer to the reaction of the same quantity of oxygen, chosen as one mole O (1 ⁄ 2 mol O 2) by some authors [2] and one mole O 2 by others. [3] The diagram shown ...
Since the metal oxide is a solid structure, both reactions must be done in the same reactor, which leads to a discontinuous production process, carrying out one step after the other. To avoid this stops in the production time, multiple reactors can be arranged to approximate a continuous production process.
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