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In addition to ammonium bicarbonate, this material contains ammonium carbamate (NH 4 CO 2 NH 2), and ammonium carbonate ((NH 4) 2 CO 3). It is sometimes called ammonium sesquicarbonate. It possesses a strong ammoniacal smell, and on digestion with alcohol, the carbamate is dissolved leaving a residue of ammonium bicarbonate. [3]
At ordinary temperatures and pressures, ammonium carbamate exists in aqueous solutions as an equilibrium with ammonia and carbon dioxide, and the anions bicarbonate, HCO − 3, and carbonate, CO 2− 3. [8] [6] [9] Indeed, solutions of ammonium carbonate or bicarbonate will contain some carbamate anions too. H 2 NCO − 2 + 2H 2 O ⇌ NH + 4 ...
In water solutions, the carbamate anion slowly equilibrates with the ammonium NH + 4 cation and the carbonate CO 2− 3 or bicarbonate HCO − 3 anions: [3] [4] [5] H 2 NCO − 2 + 2 H 2 O ⇌ NH + 4 + HCO − 3 + OH − H 2 NCO − 2 + H 2 O ⇌ NH + 4 + CO 2− 3. Calcium carbamate is soluble in water, whereas calcium carbonate is not.
Solid ammonium carbonate and ammonium bicarbonate salts partly dissociate to form NH 3, CO 2 and H 2 O vapour as follows: (NH 4) 2 CO 3 → 2 NH 3 + CO 2 + H 2 O NH 4 HCO 3 → NH 3 + CO 2 + H 2 O. The smelling salts release ammonia (NH 3) gas, which triggers an inhalation reflex.
Ammonium carbonate is produced by combining carbon dioxide and aqueous ammonia. About 80,000 tons/year were produced as of 1997. 2 NH 3 + H 2 O + CO 2 → [NH 4] 2 CO 3 [2] An orthorhombic ammonium carbonate monohydrate is known ([NH 4] 2 CO 3 ·H 2 O). It crystallizes in an ammonia solution exposed in a carbon dioxide-rich atmosphere. [3]
The bicarbonate ion (hydrogencarbonate ion) is an anion with the empirical formula HCO − 3 and a molecular mass of 61.01 daltons; it consists of one central carbon atom surrounded by three oxygen atoms in a trigonal planar arrangement, with a hydrogen atom attached to one of the oxygens.
Although di- and trivalent carbonates have low solubility, bicarbonate salts are far more soluble. This difference is related to the disparate lattice energies of solids composed of mono- vs dianions, as well as mono- vs dications. In aqueous solution, carbonate, bicarbonate, carbon dioxide, and carbonic acid participate in a dynamic equilibrium.
Ammonium bicarbonate – [NH 4]HCO 3 [35] Ammonium bisulfate – [NH 4]HSO 4 [36] ... Sodium hydrogen carbonate (Sodium bicarbonate) – NaHCO 3; Sodium hydrosulfide ...