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Arsenic acid or arsoric acid is the chemical compound with the formula H 3 AsO 4. More descriptively written as AsO(OH) 3, this colorless acid is the arsenic analogue of phosphoric acid. Arsenate and phosphate salts behave very similarly. Arsenic acid as such has not been isolated, but is only found in solution, where it is largely ionized.
The 1 H NMR spectrum of arsenous acid solutions consists of a single signal consistent with the molecule's high symmetry. [3] In contrast, the nominally related phosphorous acid H 3 PO 3 adopts the structure HPO(OH) 2. The structural analogue of arsenous acid (P(OH) 3) is a very minor equilibrium component of such solutions. The differing ...
At a given pH, the distribution of these arsenate species can be determined from their respective acid dissociation constants. [17] H 3 AsO 4 + H 2 O ⇌ H 2 AsO − 4 + [H 3 O] + (pK a1 = 2.19) H 2 AsO − 4 + H 2 O ⇌ HAsO 2− 4 + [H 3 O] + (pK a2 = 6.94) HAsO 2− 4 + H 2 O ⇌ AsO 3− 4 + [H 3 O] + (pK a3 = 11.5) These values are similar ...
Arsonic acid is the simplest of the arsonic acids. It is a hypothetical compound , although the tautomeric arsenious acid (As(OH) 3 ) is well established. In contrast to the instability of HAsO(OH) 2 , the phosphorus compound with analogous stoichiometry exists as the tetrahedral tautomer.
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Arsenic pentafluoride (AsF 5) is the only important pentahalide, reflecting the lower stability of the +5 oxidation state; even so, it is a very strong fluorinating and oxidizing agent. (The pentachloride is stable only below −50 °C, at which temperature it decomposes to the trichloride, releasing chlorine gas.
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