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For example, such a regulation might limit the concentration of NOx to 55 ppmv in a dry combustion exhaust gas corrected to 3 volume percent O 2. As another example, a regulation might limit the concentration of particulate matter to 0.1 grain per standard cubic foot (i.e., scf) of dry exhaust gas corrected to 12 volume percent CO 2 .
Equation 4 relates the concentrations of NO x and ozone, and is known as the Leighton relationship. The time τ {\displaystyle \tau } that is needed to reach a steady state among NO x and ozone is dominated by reaction ( 3 ), which reverses reactions ( 1 )+( 2 ):
The conversion equations depend on the temperature at which the conversion is wanted (usually about 20 to 25 °C). At an ambient sea level atmospheric pressure of 1 atm (101.325 kPa or 1.01325 bar ), the general equation is:
Ammonia flow is in general controlled based on NOx measurements taken from the gas stream or preexisting performance curves from an engine manufacturer (in the case of gas turbines and reciprocating engines). Typically, all future operating conditions must be known beforehand to properly design and tune an SCR system.
Selective non-catalytic reduction (SNCR) is a method to lessen nitrogen oxide emissions in conventional power plants that burn biomass, waste and coal.The process involves injecting either ammonia or urea into the firebox of the boiler at a location where the flue gas is between 1,400 and 2,000 °F (760 and 1,090 °C) to react with the nitrogen oxides formed in the combustion process.
A NO x adsorber is designed to reduce oxides of nitrogen emitted in the exhaust gas of a lean burn internal combustion engine.Lean burn engines, particularly diesels, present a special challenge to emission control system designers because of the relatively high levels of O 2 (atmospheric oxygen) in the exhaust gas.
The term NO x represents several forms of nitrogen oxides such as NO (nitric oxide), NO 2 (nitrogen dioxide) and N 2 O (nitrous oxide, also known as laughing gas).In a gasoline engine, NO is the most common form of NO x at around 93%, while NO 2 is around 5% and the rest is N 2 O.
In chemistry, the mass fraction of a substance within a mixture is the ratio (alternatively denoted ) of the mass of that substance to the total mass of the mixture. [1] ...