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  2. Full configuration interaction - Wikipedia

    en.wikipedia.org/wiki/Full_configuration_interaction

    Full configuration interaction [1] (or full CI) is a linear variational approach which provides numerically exact solutions (within the infinitely flexible complete basis set) to the electronic time-independent, non-relativistic Schrödinger equation.

  3. Configuration interaction - Wikipedia

    en.wikipedia.org/wiki/Configuration_interaction

    Configuration interaction (CI) is a post-Hartree–Fock linear variational method for solving the nonrelativistic Schrödinger equation within the Born–Oppenheimer approximation for a quantum chemical multi-electron system. Mathematically, configuration simply describes the linear combination of Slater determinants used for the

  4. Davidson correction - Wikipedia

    en.wikipedia.org/wiki/Davidson_correction

    The Davidson correction is an energy correction often applied in calculations using the method of truncated configuration interaction, which is one of several post-Hartree–Fock ab initio quantum chemistry methods in the field of computational chemistry. It was introduced by Ernest R. Davidson. [1]

  5. Electronic correlation - Wikipedia

    en.wikipedia.org/wiki/Electronic_correlation

    Dynamical correlation is the correlation of the movement of electrons and is described under electron correlation dynamics [3] and also with the configuration interaction (CI) method. Static correlation is important for molecules where the ground state is well described only with more than one (nearly-)degenerate determinant.

  6. SPIN model checker - Wikipedia

    en.wikipedia.org/wiki/SPIN_model_checker

    SPIN is a general tool for verifying the correctness of concurrent software models in a rigorous and mostly automated fashion. It was written by Gerard J. Holzmann and others in the original Unix group of the Computing Sciences Research Center at Bell Labs, beginning in 1980.

  7. Modern valence bond theory - Wikipedia

    en.wikipedia.org/wiki/Modern_valence_bond_theory

    Configuration interaction Coupled cluster Multi-configurational self-consistent field Quantum chemistry composite methods Quantum Monte Carlo: Density functional theory; Time-dependent density functional theory Thomas–Fermi model Orbital-free density functional theory Linearized augmented-plane-wave method Projector augmented wave method

  8. Coupled cluster - Wikipedia

    en.wikipedia.org/wiki/Coupled_cluster

    Configuration interaction Coupled cluster Multi-configurational self-consistent field Quantum chemistry composite methods Quantum Monte Carlo: Density functional theory; Time-dependent density functional theory Thomas–Fermi model Orbital-free density functional theory Linearized augmented-plane-wave method Projector augmented wave method

  9. Multireference configuration interaction - Wikipedia

    en.wikipedia.org/wiki/Multireference...

    In quantum chemistry, the multireference configuration interaction (MRCI) method consists of a configuration interaction expansion of the eigenstates of the electronic molecular Hamiltonian in a set of Slater determinants which correspond to excitations of the ground state electronic configuration but also of some excited states.