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A black solid, it is one of the two stable oxides of copper, the other being Cu 2 O or copper(I) oxide (cuprous oxide). As a mineral , it is known as tenorite , or sometimes black copper. It is a product of copper mining and the precursor to many other copper-containing products and chemical compounds.
Paramelaconite (Cu 4 O 3) is less well characterized. [1] Copper oxide may refer to: Copper(I) oxide (cuprous oxide, Cu 2 O) Copper(II) oxide (cupric oxide, CuO) Copper peroxide (CuO 2), a hypothetical compound; Paramelaconite (copper(I,II) oxide, Cu 4 O 3) Copper(III) oxide (Cu 2 O 3) does not exist although Cu(III) is a component of cuprate ...
Copper(I) oxide or cuprous oxide is the inorganic compound with the formula Cu 2 O. It is one of the principal oxides of copper, the other being copper(II) oxide or cupric oxide (CuO).The compound can appear either yellow or red, depending on the size of the particles. [2]
Yttrium barium copper oxide (YBa 2 Cu 3 O 7) consists of both Cu(II) and Cu(III) centres. Like oxide, fluoride is a highly basic anion [19] and is known to stabilize metal ions in high oxidation states. Both copper(III) and even copper(IV) fluorides are known, K 3 CuF 6 and Cs 2 CuF 6, respectively. [1]
Copper peroxide is a hypothetical inorganic compound with the chemical formula Cu O 2. The 1:2 ratio of copper and oxygen would be consistent with copper in its common +2 oxidation state and a peroxide group. Although samples of this composition have not been isolated, CuO 2 has attracted interest from computational perspective.
Cuprate superconductors usually feature copper oxides in both the oxidation states 3+ and 2+. For example, YBa 2 Cu 3 O 7 is described as Y 3+ (Ba 2+) 2 (Cu 3+)(Cu 2+) 2 (O 2−) 7. The copper 2+ and 3+ ions tend to arrange themselves in a checkerboard pattern, a phenomenon known as charge ordering. [8]
The standard Gibbs free energy of formation (G f °) of a compound is the change of Gibbs free energy that accompanies the formation of 1 mole of a substance in its standard state from its constituent elements in their standard states (the most stable form of the element at 1 bar of pressure and the specified temperature, usually 298.15 K or 25 °C).
Electron affinity can be defined in two equivalent ways. First, as the energy that is released by adding an electron to an isolated gaseous atom. The second (reverse) definition is that electron affinity is the energy required to remove an electron from a singly charged gaseous negative ion.