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The reactivity of a functional group can be modified by other functional groups nearby. Functional group interconversion can be used in retrosynthetic analysis to plan organic synthesis. A functional group is a group of atoms in a molecule with distinctive chemical properties, regardless of the other atoms in the molecule. The atoms in a ...
In organic chemistry, functionality is often used as a synonym for functional group. For example, a hydroxyl group can also be called a HO-function. [1] [2] Functionalisation means the introduction of functional groups, for example the functionalisation of a surface [3] (e.g. silanization for the specific modification of the adhesion of a surface)
Examples of early transition metal catalysts includes titanium and zirconium complexes. Early transition metals can easily form oxides; therefore, protection groups, like the use of methylaluminoxane (MAO) due to its Lewis acidity, can be used to prevent side reactions from happening. [13]
End groups are seen on all polymers and the functionality of those end groups can be important in determining the application of polymers. Each type of polymerization (free radical, condensation or etc.) has end groups that are typical for the polymerization, and knowledge of these can help to identify the type of polymerization method used to form the polymer.
Polymer chemistry is a sub-discipline of chemistry that focuses on the structures, chemical synthesis, and chemical and physical properties of polymers and macromolecules. The principles and methods used within polymer chemistry are also applicable through a wide range of other chemistry sub-disciplines like organic chemistry , analytical ...
The monofunctional reactant not only limits polymerization but end-caps the oligomer with functional groups capable of subsequent reaction to achieve curing of the oligomer. Functional groups like alkyne, norbornene, maleimide, nitrite, and cyanate have been used for this purpose. Maleimide and norbornene end-capped oligomers can be cured by ...
In organic chemistry, an imide is a functional group consisting of two acyl groups bound to nitrogen. [1] The compounds are structurally related to acid anhydrides, although imides are more resistant to hydrolysis. In terms of commercial applications, imides are best known as components of high-strength polymers, called polyimides.
The entrapment of catalytically active noble metals can be accomplished by grafting on functional groups to the unsaturated metal site on MOFs. Ethylenediamine (ED) has been shown to be grafted on the Cr metal sites and can be further modified to encapsulate noble metals such as Pd. [ 68 ]