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Electronegativity is not a uniquely defined property and may depend on the definition. The suggested values are all taken from WebElements as a consistent set. Many of the highly radioactive elements have values that must be predictions or extrapolations, but are unfortunately not marked as such.
Chlorine is a chemical element; it has symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between them. Chlorine is a yellow-green gas at room temperature.
It is to be expected that the electronegativity of an element will vary with its chemical environment, [7] but it is usually considered to be a transferable property, that is to say that similar values will be valid in a variety of situations. Caesium is the least electronegative element (0.79); fluorine is the most (3.98).
Fluorine's chemistry is dominated by its strong tendency to gain an electron. It is the most electronegative element and elemental fluorine is a strong oxidant. The removal of an electron from a fluorine atom requires so much energy that no known reagents are known to oxidize fluorine to any positive oxidation state. [20]
For example, the chemically very active nonmetals fluorine, chlorine, bromine, and iodine have an average electronegativity of 3.19—a figure [i] higher than that of any metallic element. The chemical distinctions between metals and nonmetals is connected to the attractive force between the positive nuclear charge of an individual atom and its ...
Chlorine (symbol Cl) is the second-lightest halogen. The element forms diatomic molecules under standard conditions, called dichlorine. It has the highest electron affinity and the one of highest electronegativity of all the elements; thus chlorine is a strong oxidizing agent.
Because carbon is more electronegative than hydrogen, the electron density in a C-H bond will be shortened and the C-F bond will be elongated. The same trend also holds for the chlorinated analogs of methane, although the effect is less dramatic because chlorine is less electronegative than fluorine. [2]
The trifluoromethyl group has a significant electronegativity that is often described as being intermediate between the electronegativities of fluorine and chlorine. [1] For this reason, trifluoromethyl-substituted compounds are often strong acids, such as trifluoromethanesulfonic acid and trifluoroacetic acid.