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Allicin features the thiosulfinate functional group, R-S-(O)-S-R. The compound is not present in garlic unless tissue damage occurs, [1] and is formed by the action of the enzyme alliinase on alliin. [1] Allicin is chiral but occurs naturally only as a racemate. [7] The racemic form can also be generated by oxidation of diallyl disulfide: [8] [9]
Staphylococcus aureus. Colorized scanning electron micrograph of a human neutrophil ingesting MRSA. Methicillin-resistant Staphylococcus aureus (MRSA) is a group of gram-positive bacteria that are genetically distinct from other strains of Staphylococcus aureus. MRSA is responsible for several difficult-to-treat infections in humans.
Vinyldithiin. Vinyldithiins, more precisely named 3-vinyl-4 H -1,2-dithiin and 2-vinyl-4 H -1,3-dithiin, are organosulfur phytochemicals formed in the breakdown of allicin from crushed garlic (Allium sativum). Vinyldithiins are Diels-Alder dimers of thioacrolein, H 2 C=CHCH=S, formed in turn by decomposition of allicin. [1]
Ceftaroline fosamil (INN) / sɛfˈtæroʊliːn /, brand name Teflaro in the US and Zinforo in Europe, [1][2] is a cephalosporin antibiotic with anti-MRSA activity. [3] Ceftaroline fosamil is a prodrug of ceftaroline. It is active against methicillin-resistant Staphylococcus aureus (MRSA) and other Gram-positive bacteria.
Using antibiotic-free alternatives in bone infection treatment may help decrease the use of antibiotics and thus antimicrobial resistance. [54] The bone regeneration material bioactive glass S53P4 has shown to effectively inhibit the bacterial growth of up to 50 clinically relevant bacteria including MRSA and MRSE. [259] [260] [261]
Alliinase. In enzymology, an alliin lyase (EC 4.4.1.4) is an enzyme that catalyzes the chemical reaction. Hence, this enzyme has one substrate, S -alkyl- L - cysteine S -oxide, and two products, alkyl sulfenate and 2-aminoacrylate. This enzyme belongs to the family of lyases, specifically the class of carbon-sulfur lyases.
Diallyl trisulfide. Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Diallyl trisulfide (DATS), also known as Allitridin, is an organosulfur compound with the formula S (SCH 2 CH=CH 2) 2. It is one of several compounds produced by hydrolysis of allicin, including diallyl disulfide ...
Allicin, S-benzyl phenylmethanethiosulfinate, and related thiosulfinates show radical-trapping antioxidant activity associated with easy formation of sulfenic acids [12] The acyclic thiosulfinates from Allium and Brassica species possess antimicrobial, antiparasitic, antitumor and cysteine protease inhibitory activity while the natural 1,2-dithiolane-1-oxides are growth inhibitors.