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A hydrogen atom is an atom of the chemical element hydrogen. The electrically neutral hydrogen atom contains a single positively charged proton in the nucleus, and a single negatively charged electron bound to the nucleus by the Coulomb force. Atomic hydrogen constitutes about 75% of the baryonic mass of the universe. [1]
In atomic physics, a partial charge (or net atomic charge) is a non-integer charge value when measured in elementary charge units. It is represented by the Greek lowercase delta (𝛿), namely 𝛿− or 𝛿+. Partial charges are created due to the asymmetric distribution of electrons in chemical bonds.
The Bohr model of the hydrogen atom (Z = 1) or a hydrogen-like ion (Z > 1), where the negatively charged electron confined to an atomic shell encircles a small, positively charged atomic nucleus and where an electron jumps between orbits, is accompanied by an emitted or absorbed amount of electromagnetic energy (hν). [1]
But the Rydberg formula also provides correct wavelengths for distant electrons, where the effective nuclear charge can be estimated as the same as that for hydrogen, since all but one of the nuclear charges have been screened by other electrons, and the core of the atom has an effective positive charge of +1.
The Mulliken population assigns an electronic charge to a given atom A, known as the gross atom population: as the sum of over all orbitals belonging to atom A. The charge, , is then defined as the difference between the number of electrons on the isolated free atom, which is the atomic number , and the gross atom population:
The rms charge radius is a measure of the size of an atomic nucleus, particularly the proton distribution. The proton radius is about one femtometre = 10 −15 metre. It can be measured by the scattering of electrons by the nucleus. Relative changes in the mean squared nuclear charge distribution can be precisely measured with atomic spectroscopy.
The Bohr radius ( ) is a physical constant, approximately equal to the most probable distance between the nucleus and the electron in a hydrogen atom in its ground state. It is named after Niels Bohr, due to its role in the Bohr model of an atom. Its value is 5.291 772 105 44 (82) × 10 −11 m. [1] [2]
The formal charge of any atom in a molecule can be calculated by the following equation: = where V is the number of valence electrons of the neutral atom in isolation (in its ground state); L is the number of non-bonding valence electrons assigned to this atom in the Lewis structure of the molecule; and B is the total number of electrons shared ...