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Hund's first rule states that the lowest energy atomic state is the one that maximizes the total spin quantum number for the electrons in the open subshell. The orbitals of the subshell are each occupied singly with electrons of parallel spin before double occupation occurs.
Hund's rule of maximum multiplicity is a rule based on observation of atomic spectra, which is used to predict the ground state of an atom or molecule with one or more open electronic shells. The rule states that for a given electron configuration , the lowest energy term is the one with the greatest value of spin multiplicity . [ 1 ]
Friedrich Hermann Hund (4 February 1896 – 31 March 1997) was a German physicist from Karlsruhe known for his work on atoms and molecules. [1] He is known for the Hund's rules to predict the electron configuration of chemical elements. His work on Hund's cases and molecular orbital theory allowed to understand the structure of molecules.
Hund's rule asserts that if multiple orbitals of the same energy are available, electrons will occupy different orbitals singly and with the same spin before any are occupied doubly. If double occupation does occur, the Pauli exclusion principle requires that electrons that occupy the same orbital must have different spins (+ 1 ⁄ 2 and − 1 ...
This spin is due to two unpaired electrons, as a result of Hund's rule which favors the single filling of degenerate orbitals. The triplet consists of three states with spin components +1, 0 and –1 along the direction of the total orbital angular momentum, which is also 1 as indicated by the letter P.
Sieverts's law, in physical metallurgy, is a rule to predict the solubility of gases in metals. Named after German chemist Adolf Sieverts (1874–1947). Smeed's law is an empirical rule relating traffic fatalities to traffic congestion as measured by the proxy of motor vehicle registrations and country population. After R. J. Smeed.
A U.S. judge overseeing an auction of shares in the parent of Venezuela-owned Citgo Petroleum on Monday agreed to reopen a data room to allow potential buyers to prepare new bids, a court document ...
Pages in category "Eponymous chemical rules" The following 22 pages are in this category, out of 22 total. ... Hund's rules; K. Kasha's rule; L. Laporte rule; M ...