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The odor of EtSH is infamous. Ethanethiol is more volatile than ethanol due to a diminished ability to engage in hydrogen bonding. Ethanethiol is toxic in high concentrations. It occurs naturally as a minor component of petroleum, and may be added to otherwise odorless gaseous products such as liquefied petroleum gas (LPG) to help warn of gas ...
A human olfactory receptor, OR2T11, has been identified which, in the presence of copper, is highly responsive to the gas odorants (see below) ethanethiol and t-butyl mercaptan as well as other low molecular weight thiols, including allyl mercaptan found in human garlic breath, and the strong-smelling cyclic sulfide thietane.
Diethyl sulfide is a by-product of the commercial production of ethanethiol, which is prepared by the reaction of ethylene with hydrogen sulfide over an alumina-based catalyst. The amount of diethyl sulfide produced can be controlled by varying the ratio of hydrogen sulfide to ethylene.
1,2-Ethanedithiol has been used as a scavenger in peptide cleavage synthesis. [citation needed] Like 1,3-propanedithiol, 1,2-ethanedithiol readily forms metal thiolate complexes. Illustrative is the synthesis of the derivative diiron ethanedithiolate hexacarbonyl upon reaction with triiron dodecacarbonyl: [5]
Cylinder of methanethiol gas. Methanethiol is mainly used to produce the essential amino acid methionine, which is used as a dietary component in poultry and animal feed. [10] Methanethiol is also used in the plastic industry as a moderator for free-radical polymerizations [10] and as a precursor in the manufacture of pesticides.
Ethanethiol, or ethyl mercaptan Index of chemical compounds with the same molecular formula This set index page lists chemical structure articles associated with the same molecular formula .
Hydrogen fuel cells are vying for a top spot among humanity’s green energy solutions, but chemicals found in fuel cells— as well as the environmental cost of producing hydrogen—are a major ...
Toxicity may be due to metabolism products hydrogen sulfide and acetaldehyde, however as used it has a margin of safety of over 10,000,000. [2] Other ways that it is modified in the body apart from hydrolysis is methylation to 1-methylsulfanyl-ethanethiol, oxidation of the sulfur to an ethyl sulfonate, glucuronidation of the sulfur, or ...