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Chloral hydrate is a geminal diol with the formula Cl 3 C−CH(OH) 2. It was first used as a sedative and hypnotic in Germany in the 1870s. Over time it was replaced by safer and more effective alternatives but it remained in usage in the United States until at least the 1970s. [ 4 ]
Chloral tends to form adducts with water (to give chloral hydrate) and alcohols. Aside from its tendency to hydrate, chloral is notable as a building block in the synthesis of DDT. For this purpose, chloral is treated with chlorobenzene in the presence of a catalytic amount of sulfuric acid: Cl 3 CCHO + 2 C 6 H 5 Cl → Cl 3 CCH(C 6 H 4 Cl) 2 ...
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Diagram of the mercury-cell process, showing an "inner" cell sandwiched between two "outer" cells, with a layer of mercury common to all three. In the mercury-cell process, also known as the Castner–Kellner process , the "outer" electrolytic cells each contain an anode immersed in brine, which floats on a layer of mercury.
Similarly, the conversion of chloral (Cl 3 C)HC =O to chloral hydrate is strongly favored by influence of the trichloromethyl group . In some cases, such as decahydroxycyclopentane and dodecahydroxycyclohexane , the geminal diol is stable while the corresponding ketone is not.
The earliest record of trichloroethylene synthesis dates back to 1836. It was obtained from the action of potassium hydroxide on 1,1,2,2-tetrachloroethane and 1,1,1,2-tetrachloroethane by Auguste Laurent and notated as C 4 HCl 3 (then the atomic weight of carbon was thought to be the half of it really was).
Chlorobutanol (trichloro-2-methyl-2-propanol) is an organic compound with the formula CCl 3 C(OH)(CH 3) 2.The compound is a chlorohydrin.The compound is a preservative, sedative, hypnotic and weak local anesthetic similar in nature to chloral hydrate.
It is advised to check the references for photos of reaction results. [1] Reagent testers might show the colour of the desired substance while not showing a different colour for a more dangerous additive. [2]