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Reactions of barium hydroxide with ammonium salts are strongly endothermic. The reaction of barium hydroxide octahydrate with ammonium chloride [18] [19] or [20] ammonium thiocyanate [20] [21] is often used as a classroom chemistry demonstration, producing temperatures cold enough to freeze water and enough water to dissolve the resulting mixture.
In place of HCl, chlorine can be used. [7] Barium chloride is extracted out from the mixture with water. From water solutions of barium chloride, its dihydrate (BaCl 2 ·2H 2 O) can be crystallized as colorless crystals. [2] Barium chloride can in principle be prepared by the reaction between barium hydroxide or barium carbonate with hydrogen ...
HCl → H + + Cl −. If HCl is added to the H 2 S solution, H + is a common ion and creates a common ion effect. Due to the increase in concentration of H + ions from the added HCl, the equilibrium of the dissociation of H 2 S shifts to the left and keeps the value of K a constant.
A neutralization reaction is a type of double replacement reaction. A neutralization reaction occurs when an acid reacts with an equal amount of a base. This reaction usually produces a salt. One example, hydrochloric acid reacts with disodium iron tetracarbonyl to produce the iron dihydride: 2 HCl + Na 2 Fe(CO) 4 → 2 NaCl + H 2 Fe(CO) 4
In the Tishchenko reaction, the base used is an alkoxide rather than hydroxide, and the product is an ester rather than the separate alcohol and carboxylate groups. After the nucleophilic base attacks an aldehyde, the resulting new oxygen anion attacks another aldehyde to give a hemiacetal linkage between two of the formerly aldehyde-containing ...
For example, hydrochloric acid, HCl, is a strong acid. HCl(aq) → H + (aq) + Cl − (aq) A strong base is one that is fully dissociated in aqueous solution. For example, sodium hydroxide, NaOH, is a strong base. NaOH(aq) → Na + (aq) + OH − (aq) Therefore, when a strong acid reacts with a strong base the neutralization reaction can be ...
Barbier reaction with samarium(II) iodide. The Barbier reaction is an organometallic reaction between an alkyl halide (chloride, bromide, iodide), a carbonyl group and a metal. The reaction can be performed using magnesium, aluminium, zinc, indium, tin, samarium, barium or their salts. The reaction product is a primary, secondary or tertiary ...
Ketonic decarboxylation (also known as decarboxylative ketonization) is a type of organic reaction involving decarboxylation, converting two equivalents of a carboxylic acid (R−C(=O)OH) to a symmetric ketone (R 2 C=O). The reaction typically requires heat and a metal catalyst, and generally proceeds in low yields.