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Liquid carbon dioxide is the liquid state of carbon dioxide (CO 2 ), which cannot occur under atmospheric pressure. It can only exist at a pressure above 5.1 atm (5.2 bar; 75 psi), under 31.1 °C (88.0 °F) (temperature of critical point ) and above −56.6 °C (−69.9 °F) (temperature of triple point ). [ 1 ]
Otherwise temperature is equilibrium of vapor over liquid. For kPa values, where datum is whole numbers of atmospheres exact kPa values are given, elsewhere 2 significant figures derived from mm Hg data. log of Carbon Dioxide vapor pressure.
Supercritical carbon dioxide (s CO 2 ) is a fluid state of carbon dioxide where it is held at or above its critical temperature and critical pressure . Carbon dioxide usually behaves as a gas in air at standard temperature and pressure (STP), or as a solid called dry ice when cooled and/or pressurised sufficiently.
Non ideal compressible fluid dynamics (NICFD), or non ideal gas dynamics, is a branch of fluid mechanics studying the dynamic behavior of fluids not obeying ideal-gas thermodynamics. It is for example the case of dense vapors , supercritical flows and compressible two-phase flows .
Supercritical carbon dioxide sometimes intercalates into buttons, and, when the SCD is depressurized, the buttons pop, or break apart. Detergents that are soluble in carbon dioxide improve the solvating power of the solvent. [20] CO 2-based dry cleaning equipment uses liquid CO 2, not supercritical CO 2, to avoid damage to the buttons.
The term inert gas is context-dependent because several of the inert gases, including nitrogen and carbon dioxide, can be made to react under certain conditions. [ 1 ] [ 2 ] Purified argon gas is the most commonly used inert gas due to its high natural abundance (78.3% N 2 , 1% Ar in air) [ 3 ] and low relative cost.
The symmetry of a carbon dioxide molecule is linear and centrosymmetric at its equilibrium geometry. The length of the carbon–oxygen bond in carbon dioxide is 116.3 pm, noticeably shorter than the roughly 140 pm length of a typical single C–O bond, and shorter than most other C–O multiply bonded functional groups such as carbonyls. [19]
Liquid carbon dioxide can be stored at ambient temperatures, unlike Liquid air energy storage (LAES), which must keep liquid air cold at −192°C, though the CO 2 does need to be kept pressurised. Liquid CO 2 has a much higher energy density (66.7 kWh/m 3 ), than compressed air in typical to compressed-air energy storage (CAES) systems (2-6 ...