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Triplet oxygen, 3 O 2, refers to the S = 1 electronic ground state of molecular oxygen (dioxygen). Molecules of triplet oxygen contain two unpaired electrons, making triplet oxygen an unusual example of a stable and commonly encountered diradical : [ 2 ] it is more stable as a triplet than a singlet .
Singlet oxygen is the common name used for the two metastable states of molecular oxygen (O 2) with higher energy than the ground state triplet oxygen. Because of the differences in their electron shells, singlet oxygen has different chemical and physical properties than triplet oxygen, including absorbing and emitting light at different ...
The two singlet-triplet transitions are forbidden both because of the spin selection rule ΔS = 0 and because of the parity rule that g-g transitions are forbidden. [11] The singlet-singlet transition between the two excited states is spin-allowed but parity-forbidden. The lower, O 2 (1 Δ g) state is commonly referred to as singlet oxygen.
Most molecules encountered in daily life exist in a singlet state because all of their electrons are paired, but molecular oxygen is an exception. [1] At room temperature, O 2 exists in a triplet state, which can only undergo a chemical reaction by making the forbidden transition into a singlet state. This makes it kinetically nonreactive ...
The molecule, therefore, has two unpaired electrons and is in a triplet state. In contrast, the first and second excited states of dioxygen are both states of singlet oxygen. Each has two electrons of opposite spin in the π* level so that S = 0 and the multiplicity is 2S + 1 = 1 in consequence.
Singlet oxygen (1 O 2) is sometimes included as an ROS. Photosensitizers such as chlorophyll may convert triplet (3 O 2) to singlet oxygen: [6] Singlet oxygen is highly reactive with unsaturated organic compounds. Carotenoids, tocopherols, and plastoquinones contained in
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As in diboron, these two unpaired electrons have the same spin in the ground state, which is a paramagnetic diradical triplet oxygen. The first excited state has both HOMO electrons paired in one orbital with opposite spins, and is known as singlet oxygen. MO diagram of dioxygen triplet ground state