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  2. Equilibrium constant - Wikipedia

    en.wikipedia.org/wiki/Equilibrium_constant

    The concentration of the species LH is equal to the sum of the concentrations of the two micro-species with the same chemical formula, labelled L 1 H and L 2 H. The constant K 2 is for a reaction with these two micro-species as products, so that [LH] = [L 1 H] + [L 2 H] appears in the numerator, and it follows that this macro-constant is equal ...

  3. Determination of equilibrium constants - Wikipedia

    en.wikipedia.org/wiki/Determination_of...

    The chemical model consists of a set of chemical species present in solution, both the reactants added to the reaction mixture and the complex species formed from them. Denoting the reactants by A, B..., each complex species is specified by the stoichiometric coefficients that relate the particular combination of reactants forming them.

  4. Graphite intercalation compound - Wikipedia

    en.wikipedia.org/wiki/Graphite_intercalation...

    [4] [5] KC 8 is a superconductor with a very low critical temperature T c = 0.14 K. [6] Heating KC 8 leads to the formation of a series of decomposition products as the K atoms are eliminated: [citation needed] 3 KC 8 → KC 24 + 2 K. Via the intermediates KC 24 (blue in color), [3] KC 36, KC 48, ultimately the compound KC 60 results.

  5. Benesi–Hildebrand method - Wikipedia

    en.wikipedia.org/wiki/Benesi–Hildebrand_method

    This method was first developed by Benesi and Hildebrand in 1949, [2] as a means to explain a phenomenon where iodine changes color in various aromatic solvents. This was attributed to the formation of an iodine-solvent complex through acid-base interactions, leading to the observed shifts in the absorption spectrum.

  6. Van 't Hoff equation - Wikipedia

    en.wikipedia.org/wiki/Van_'t_Hoff_equation

    The Van 't Hoff equation relates the change in the equilibrium constant, K eq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, Δ r H ⊖, for the process. The subscript r {\displaystyle r} means "reaction" and the superscript ⊖ {\displaystyle \ominus } means "standard".

  7. Table of thermodynamic equations - Wikipedia

    en.wikipedia.org/wiki/Table_of_thermodynamic...

    Quantity (common name/s) (Common) symbol/s Defining equation SI unit Dimension Temperature gradient: No standard symbol K⋅m −1: ΘL −1: Thermal conduction rate, thermal current, thermal/heat flux, thermal power transfer

  8. Reaction rate constant - Wikipedia

    en.wikipedia.org/wiki/Reaction_rate_constant

    where A and B are reactants C is a product a, b, and c are stoichiometric coefficients,. the reaction rate is often found to have the form: = [] [] Here ⁠ ⁠ is the reaction rate constant that depends on temperature, and [A] and [B] are the molar concentrations of substances A and B in moles per unit volume of solution, assuming the reaction is taking place throughout the volume of the ...

  9. Extent of reaction - Wikipedia

    en.wikipedia.org/wiki/Extent_of_reaction

    In physical chemistry and chemical engineering, extent of reaction is a quantity that measures the extent to which the reaction has proceeded. Often, it refers specifically to the value of the extent of reaction when equilibrium has been reached. It is usually denoted by the Greek letter ξ.