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Partition coefficients can also be defined when one of the phases is solid, for instance, when one phase is a molten metal and the second is a solid metal, [6] or when both phases are solids. [7] The partitioning of a substance into a solid results in a solid solution.
In thermodynamics, the ebullioscopic constant K b relates molality b to boiling point elevation. [1] It is the ratio of the latter to the former: = i is the van 't Hoff factor, the number of particles the solute splits into or forms when dissolved. b is the molality of the solution.
In chemistry, a formula unit is the smallest unit of a non-molecular substance, such as an ionic compound, covalent network solid, or metal. [1] [2] It can also refer to the chemical formula for that unit. Those structures do not consist of discrete molecules, and so for them, the term formula unit is used.
The SI unit of molar absorption coefficient is the square metre per mole (m 2 /mol), but in practice, quantities are usually expressed in terms of M −1 ⋅cm −1 or L⋅mol −1 ⋅cm −1 (the latter two units are both equal to 0.1 m 2 /mol). In older literature, the cm 2 /mol is sometimes used; 1 M −1 ⋅cm −1 equals 1000 cm 2 /mol.
The n-octanol-water partition coefficient, K ow is a partition coefficient for the two-phase system consisting of n-octanol and water. [1] K ow is also frequently referred to by the symbol P, especially in the English literature. It is also called n-octanol-water partition ratio. [2] [3] [4]
If the solute is volatile, one of the key assumptions used in deriving the formula is not true because the equation derived is for solutions of non-volatile solutes in a volatile solvent. In the case of volatile solutes, the equation can represent a mixture of volatile compounds more accurately, and the effect of the solute on the boiling point ...
The Sackur–Tetrode constant, written S 0 /R, is equal to S/k B N evaluated at a temperature of T = 1 kelvin, at standard pressure (100 kPa or 101.325 kPa, to be specified), for one mole of an ideal gas composed of particles of mass equal to the atomic mass constant (m u = 1.660 539 068 92 (52) × 10 −27 kg [5]).
When B / C > 1, B is the favored product, and the data on the Van 't Hoff plot will be in the positive region. When B / C < 1, C is the favored product, and the data on the Van 't Hoff plot will be in the negative region. Using this information, a Van 't Hoff analysis can help determine the most suitable temperature for a ...