Search results
Results From The WOW.Com Content Network
In practice, the mercury adduct product created by the oxymercuration reaction is almost always treated with sodium borohydride (NaBH 4) in aqueous base in a reaction called demercuration. In demercuration, the acetoxymercury group is replaced with a hydrogen in a stereochemically insensitive reaction [6] known as reductive elimination. The ...
Alkene oxymercuration-demercuration: Stereospecific: Can only be anti addition – water kicks out the mercury from underneath the intermediate three-membered ring. The reaction is considered Markovnikov as it results in water addition with same regiospecificity as a direct hydration reaction. Alkene hydroboration-oxidation
Meaning Origin language and etymology Example(s) dacry(o)-of or pertaining to tears: Greek δάκρυ, tear dacryoadenitis, dacryocystitis-dactyl(o)-of or pertaining to a finger, toe Greek δάκτυλος (dáktulos), finger, toe dactylology, polydactyly: de-from, down, or away from Latin de-dehydrate, demonetize, demotion dent-
Meaning [1] Latin (or Neo-Latin) origin [1] a.c. before meals: ante cibum a.d., ad, AD right ear auris dextra a.m., am, AM morning: ante meridiem: nocte every night Omne Nocte a.s., as, AS left ear auris sinistra a.u., au, AU both ears together or each ear aures unitas or auris uterque b.d.s, bds, BDS 2 times a day bis die sumendum b.i.d., bid, BID
Conversion of 2,5-dimethylhexyne-2,5-diol to 2,2,5,5-tetramethylte-trahydrofuran-3-one. Mercury sulfate, as well as other mercury(II) compounds, are commonly used as catalysts in oxymercuration-demercuration, a type of electrophilic addition reaction that results in hydration of an unsaturated compound.
Pages for logged out editors learn more. Contributions; Talk; Oxymercuration-demercuration
This is a list of abbreviations used in medical prescriptions, including hospital orders (the patient-directed part of which is referred to as sig codes). This list does not include abbreviations for pharmaceuticals or drug name suffixes such as CD, CR, ER, XT (See Time release technology § List of abbreviations for those).
For example diphenylmercury reacts with aluminium gives triphenyl aluminium: 3 (C 6 H 5) 2 Hg + 2 Al → Al(C 6 H 5) 3) 2 + 3 Hg. As indicated above, organomercury compounds react with halogens to give the corresponding organic halide. Phenyl(trichloromethyl)mercury can be prepared by generating dichlorocarbene in the presence of phenylmercuric ...