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Such covalent substances are low-boiling-temperature liquids (such as ethanol), and low-melting-temperature solids (such as iodine and solid CO 2). Macromolecular structures have large numbers of atoms linked by covalent bonds in chains, including synthetic polymers such as polyethylene and nylon, and biopolymers such as proteins and starch.
This Wikipedia page provides a comprehensive list of boiling and freezing points for various solvents.
Molecular solids have low melting (T m) and boiling (T b) points compared to metal (iron), ionic (sodium chloride), and covalent solids (diamond). [4] [5] [8] [13] Examples of molecular solids with low melting and boiling temperatures include argon, water, naphthalene, nicotine, and caffeine (see table below).
Ionic bonding is a type of electrostatic interaction between atoms that have a large electronegativity difference. There is no precise value that distinguishes ionic from covalent bonding, but an electronegativity difference of over 1.7 is likely to be ionic while a difference of less than 1.7 is likely to be covalent. [21] Ionic bonding leads ...
Melting points are typically moderately high, but some combinations of molecular cations and anions yield an ionic liquid with a freezing point below room temperature. Vapour pressures in all instances are extraordinarily low; this is a consequence of the large energy required to move a bare charge (or charge pair) from an ionic medium into ...
In such cases, the compounds generally have very high melting and boiling points and a low vapour pressure. [61] Trends in melting points can be even better explained when the structure and ionic size ratio is taken into account. [ 62 ]
Although hydrogen bonding is a relatively weak attraction compared to the covalent bonds within the water molecule itself, it is responsible for several of the water's physical properties. These properties include its relatively high melting and boiling point temperatures: more energy is required to break the hydrogen bonds between water molecules.
The classical model identifies three main types of chemical bonds — ionic, covalent, and metallic — distinguished by the degree of charge separation between participating atoms. [3] The characteristics of the bond formed can be predicted by the properties of constituent atoms, namely electronegativity.