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Lithium nitrate is an inorganic compound with the formula LiNO 3. It is the lithium salt of nitric acid (an alkali metal nitrate ). The salt is deliquescent , absorbing water to form the hydrated form, lithium nitrate trihydrate.
A recommended laboratory synthesis entails dehydrating nitric acid (HNO 3) with phosphorus(V) oxide: [11] P 4 O 10 + 12 HNO 3 → 4 H 3 PO 4 + 6 N 2 O 5. Another laboratory process is the reaction of lithium nitrate LiNO 3 and bromine pentafluoride BrF 5, in the ratio exceeding 3:1.
Lithium nitrite is the lithium salt of nitrous acid, with formula LiNO 2. This compound is hygroscopic and very soluble in water. It is used as a corrosion inhibitor in mortar. [4] It is also used in the production of explosives, due to its ability to nitrosate ketones under certain conditions. [5]
Lithium nitride is prepared by direct reaction of elemental lithium with nitrogen gas: [2] 6 Li + N 2 → 2 Li 3 N. Instead of burning lithium metal in an atmosphere of nitrogen, a solution of lithium in liquid sodium metal can be treated with N 2. Lithium nitride must be protected from moisture as it reacts violently with water to produce ammonia:
The standard Gibbs free energy of formation (G f °) of a compound is the change of Gibbs free energy that accompanies the formation of 1 mole of a substance in its standard state from its constituent elements in their standard states (the most stable form of the element at 1 bar of pressure and the specified temperature, usually 298.15 K or 25 °C).
Sol–gel methods are another common NMC synthesis method. In this method, transition metal precursors are dissolved in a nitrate or acetate solution, then combined with a lithium nitrate or lithium acetate and citric acid solution. This mixture is stirred and heated to about 80 °C under basic conditions until a viscous gel forms. The gel is ...
Ammonium nitrate decomposition (as monopropellant) 1.4: 2.5: Thermal Energy Capacity of Molten Salt: 1 [citation needed] 98% [18] Molecular spring approximate [citation needed] 1: battery, Lithium–Manganese [19] [20] 0.83-1.01: 1.98-2.09: battery, Sodium–Sulfur: 0.72 [21] 1.23 [citation needed] 85% [22] battery, Lithium-ion [23] [24] 0.46-0 ...
The nitrate ion. Alkali metal nitrates are chemical compounds consisting of an alkali metal (lithium, sodium, potassium, rubidium and caesium) and the nitrate ion. Only two are of major commercial value, the sodium and potassium salts. [1] They are white, water-soluble salts with melting points ranging from 255 °C (LiNO 3) to 414 °C (CsNO