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Constant-pressure simulations are useful for determining the equation of state of a pure system. Monte Carlo simulations using the -ensemble are particularly useful for determining the equation of state of fluids at pressures of around 1 atm, where they can achieve accurate results with much less computational time than other ensembles.
Thermodynamic diagrams usually show a net of five different lines: isobars = lines of constant pressure; isotherms = lines of constant temperature; dry adiabats = lines of constant potential temperature representing the temperature of a rising parcel of dry air
An isothermal process is a type of thermodynamic process in which the temperature T of a system remains constant: ΔT = 0. This typically occurs when a system is in contact with an outside thermal reservoir, and a change in the system occurs slowly enough to allow the system to be continuously adjusted to the temperature of the reservoir through heat exchange (see quasi-equilibrium).
Isobar may refer to: Isobar (meteorology), a line connecting points of equal atmospheric pressure reduced to sea level on the maps. Isobaric process, a process taking place at constant pressure; Isobar (nuclide), one of multiple nuclides with the same mass but with different numbers of protons (or, equivalently, different numbers of neutrons).
The dependence of work on the path of the thermodynamic process is also unrelated to reversibility, since expansion work, which can be visualized on a pressure–volume diagram as the area beneath the equilibrium curve, is different for different reversible expansion processes (e.g. adiabatic, then isothermal; vs. isothermal, then adiabatic ...
Heat flows into the loop through the top isotherm and the left isochore, and some of this heat flows back out through the bottom isotherm and the right isochore, but most of the heat flow is through the pair of isotherms. This makes sense since all the work done by the cycle is done by the pair of isothermal processes, which are described by Q ...
An isobar (from Ancient Greek βάρος (baros) 'weight') is a line of equal or constant pressure on a graph, plot, or map; an isopleth or contour line of pressure. More accurately, isobars are lines drawn on a map joining places of equal average atmospheric pressure reduced to sea level for a specified period of time.
Simplified temperature/pressure phase change diagram for water. The pressure on a pressure-temperature diagram (such as the water phase diagram shown above) is the partial pressure of the substance in question.