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Chlorine pentafluoride is an interhalogen compound with formula ClF 5. This colourless gas is a strong oxidant that was once a candidate oxidizer for rockets. The molecule adopts a square pyramidal structure with C 4v symmetry, [1] as confirmed by its high-resolution 19 F NMR spectrum. [2] It was first synthesized in 1963. [3]
Structure of xenon oxytetrafluoride, an example of a molecule with the square pyramidal coordination geometry. Square pyramidal geometry describes the shape of certain chemical compounds with the formula ML 5 where L is a ligand. If the ligand atoms were connected, the resulting shape would be that of a pyramid with a square base.
The compounds are weak Lewis bases, with NF 3 again being an exception. [84] The pentafluorides of phosphorus [85] and arsenic [86] are much more reactive than their trifluorides; antimony pentafluoride is such a strong acid that it holds the title of the strongest Lewis acid. [86]
Hypervalent iodine compounds are useful reagents in organic chemistry (e.g. Dess–Martin periodinane) Tetra-, penta- and hexavalent phosphorus, silicon, and sulfur compounds (e.g. PCl 5, PF 5, SF 6, sulfuranes and persulfuranes) Noble gas compounds (ex. xenon tetrafluoride, XeF 4) Halogen polyfluorides (ex. chlorine pentafluoride, ClF 5)
It is the acid fluoride of perchloric acid. In spite of its small enthalpy of formation (Δ f H° = −5.2 kcal/mol (−22 kJ/mol)), it is kinetically stable, decomposing only at 400 °C. [3]: 380 It is quite reactive towards reducing agents and anions, however, with the chlorine atom acting as an electrophile.
Chloryl fluoride is the chemical compound with the formula ClO 2 F. It is commonly encountered as side-product in reactions of chlorine fluorides with oxygen sources. [1] It is the acyl fluoride of chloric acid.
Chlorine trifluoride is an interhalogen compound with the formula ClF 3. It is a colorless, poisonous, corrosive, and extremely reactive gas that condenses to a pale-greenish yellow liquid, the form in which it is most often sold (pressurized at room temperature).
A chlorine fluoride is an interhalogen compound containing only chlorine and fluorine ... Chlorine trifluoride: Chlorine pentafluoride: Molar mass: 54.45 g/mol 92.45 ...