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  2. Orbital angular momentum of free electrons - Wikipedia

    en.wikipedia.org/wiki/Orbital_angular_momentum...

    Electrons in free space can carry quantized orbital angular momentum (OAM) projected along the direction of propagation. [1] This orbital angular momentum corresponds to helical wavefronts, or, equivalently, a phase proportional to the azimuthal angle. [2] Electron beams with quantized orbital angular momentum are also called electron vortex beams.

  3. Azimuthal quantum number - Wikipedia

    en.wikipedia.org/wiki/Azimuthal_quantum_number

    "Vector cones" of total angular momentum J (purple), orbital L (blue), and spin S (green). The cones arise due to quantum uncertainty between measuring angular momentum component. Due to the spin–orbit interaction in an atom, the orbital angular momentum no longer commutes with the Hamiltonian, nor does the spin. These therefore change over time.

  4. Landé g-factor - Wikipedia

    en.wikipedia.org/wiki/Landé_g-factor

    Here, J is the total electronic angular momentum, L is the orbital angular momentum, and S is the spin angular momentum. Because = / for electrons, one often sees this formula written with 3/4 in place of (+). The quantities g L and g S are other g-factors of an electron.

  5. g-factor (physics) - Wikipedia

    en.wikipedia.org/wiki/G-factor_(physics)

    The spin magnetic moment of a charged, spin-1/2 particle that does not possess any internal structure (a Dirac particle) is given by [1] =, where μ is the spin magnetic moment of the particle, g is the g-factor of the particle, e is the elementary charge, m is the mass of the particle, and S is the spin angular momentum of the particle (with magnitude ħ/2 for Dirac particles).

  6. Atomic orbital - Wikipedia

    en.wikipedia.org/wiki/Atomic_orbital

    Each orbital in an atom is characterized by a set of values of three quantum numbers n, ℓ, and m ℓ, which respectively correspond to electron's energy, its orbital angular momentum, and its orbital angular momentum projected along a chosen axis (magnetic quantum number). The orbitals with a well-defined magnetic quantum number are generally ...

  7. Magnetochemistry - Wikipedia

    en.wikipedia.org/wiki/Magnetochemistry

    When orbital angular momentum is completely quenched, = and the paramagnetism can be attributed to electron spin alone. The total spin angular momentum is simply half the number of unpaired electrons and the spin-only formula results. = (+) where n is the number of unpaired electrons. The spin-only formula is a good first approximation for high ...

  8. Term symbol - Wikipedia

    en.wikipedia.org/wiki/Term_symbol

    In atomic physics, a term symbol is an abbreviated description of the total spin and orbital angular momentum quantum numbers of the electrons in a multi-electron atom.So while the word symbol suggests otherwise, it represents an actual value of a physical quantity.

  9. Magnetic quantum number - Wikipedia

    en.wikipedia.org/wiki/Magnetic_quantum_number

    , the magnitude of the angular momentum in the -direction, is given by the formula: [7] L z = m l ℏ {\displaystyle L_{z}=m_{l}\hbar } . This is a component of the atomic electron's total orbital angular momentum L {\displaystyle \mathbf {L} } , whose magnitude is related to the azimuthal quantum number of its subshell ℓ {\displaystyle \ell ...