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Mesotrione is a selective herbicide used mainly in maize crops. [1] It is a synthetic compound inspired by the natural substance leptospermone found in the bottlebrush tree Callistemon citrinus. It inhibits the enzyme 4-hydroxyphenylpyruvate dioxygenase (HPPD) [3] and is sold under brand names
Leptospermone can be synthesized from phloroglucinol by a reaction with 3-methylbutanenitrile (isovaleronitrile) in the presence of a zinc chloride catalyst. . Phloroisovalerone imine is produced which is then alkylated with iodomethane after initial treatment with sodium ethoxide and methanol to produce an intermediate which is treated with aqueous hydrochloric acid resulting in ...
The industry-sponsored Herbicide Resistance Action Committee (HRAC) advises on the use of herbicides in crop protection and classifies the available compounds according to their chemical structures and mechanism of action so as to manage the risks of pesticide resistance developing. [4]
The Herbicide Resistance Action Committee (HRAC) classifies herbicides by their mode of action (MoA) to provide a uniform way for farmers and growers to identify the agents they use and better manage pesticide resistance around the world. [1] [2] It is run by CropLife International [3] in conjunction with the Weed Science Society of America ...
An example of a fully executed label compliant with the USEPA resistance management labeling guidance can be seen on the specimen label for the herbicide, cloransulam-methyl, updated in 2022. [ 81 ] Optimising herbicide input to the economic threshold level should avoid the unnecessary use of herbicides and reduce selection pressure.
The purpose of the label is to "provide clear directions for effective product performance while minimizing risk to human health and the environment." A label is a legally binding document that mandates how the pesticide can and must be used and failure to follow the label as written when using the pesticide is a federal offense. [4]