Search results
Results From The WOW.Com Content Network
In the above equation, T F is the normal freezing point of the pure solvent (273 K for water, for example); a liq is the activity of the solvent in the solution (water activity for aqueous solution); ΔH fus T F is the enthalpy change of fusion of the pure solvent at T F, which is 333.6 J/g for water at 273 K; ΔC fus p is the difference ...
The term "cryoscopy" means "freezing measurement" in Greek. Freezing point depression is a colligative property, so ΔT depends only on the number of solute particles dissolved, not the nature of those particles. Cryoscopy is related to ebullioscopy, which determines the same value from the ebullioscopic constant (of boiling point elevation).
The laboratory value measures the freezing point depression, properly called osmolality while the calculated value is given in units of osmolarity. Even though these values are presented in different units, when there is a small amount of solute compared to total volume of solution, the absolute values of osmolality vs. osmolarity are very close.
For liquid solutions, the osmotic coefficient is often used to calculate the salt activity coefficient from the solvent activity, or vice versa. For example, freezing point depression measurements, or measurements of deviations from ideality for other colligative properties, allows calculation of the salt activity coefficient through the osmotic coefficient.
The freezing point depression osmometer is an osmometer that is used in determining a solution's osmotic concentration as its osmotically active aspects depress its freezing point. In the past, freezing point osmometry has been used to assess the osmotic strength of colloids and solutions. The osmometer uses the solution's freezing point ...
Freezing point (°C) K f (°C⋅kg/mol) Data source; Aniline: 184.3 3.69 –5.96 –5.87 K b & K f [1] ... Freezing-point depression; Boiling-point elevation; References
An osmometer is a device for measuring the osmotic strength of a solution, colloid, or compound.. There are several different techniques employed in osmometry: Freezing point depression osmometers may also be used to determine the osmotic strength of a solution, as osmotically active compounds depress the freezing point of a solution.
Freezing point depression and boiling point elevation In chemistry , colligative properties are those properties of solutions that depend on the ratio of the number of solute particles to the number of solvent particles in a solution, and not on the nature of the chemical species present. [ 1 ]