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pelargonic acid 1-octanecarboxylic acid: CH 3 (CH 2) 7 COOH benzene-1,3,5-tricarboxylic acid: trimesic acid: C 6 H 3 (COOH) 3 (E)-3-phenylprop-2-enoic acid: cinnamic acid trans-cinnamic acid phenylacrylic acid cinnamylic acid 3-phenylacrylic acid (E)-cinnamic acid benzenepropenoic acid isocinnamic acid: C 6 H 5 CH=CHCOOH
acetyl chloride SOCl 2 acetic acid (i) Li[AlH 4], ether (ii) H 3 O + ethanol Two typical organic reactions of acetic acid Acetic acid undergoes the typical chemical reactions of a carboxylic acid. Upon treatment with a standard base, it converts to metal acetate and water. With strong bases (e.g., organolithium reagents), it can be doubly deprotonated to give LiCH 2 COOLi. Reduction of acetic ...
CH 3 CO 2 H: acetic acid: 64-19-7 (CH 3) 2 CO: acetone: 67-64-1 CH 3 CN: acetonitrile: 75-05-8 CH 3 CH 2 CH(OH)CH 2 OH: 1,2-Butanediol: 584-03-2 CH 3 CH(OH)CH 2 CH 2 OH: 1,3-Butanediol: 107-88-0 HOCH 2 CH 2 CH 2 CH 2 OH: 1,4-Butanediol: 110-63-4 C 6 H 14 O 2: 2-Butoxyethanol: 111-76-2 CH 3 CH 2 CH 2 COOH: butyric acid: 107-92-6 HN(CH 2 CH 2 OH ...
Ethyl glyoxylate 2 and glutaconate (diethyl-2-methylpent-2-enedioate) 1 react to isoprenetricarboxylic acid 3 (isoprene (2-methylbuta-1,3-diene) skeleton) with sodium ethoxide. This reaction product is very unstable with initial loss of carbon dioxide and followed by many secondary reactions.
The active hydrogen component has the forms: [3] Z−CH 2 −Z or Z−CHR−Z for instance diethyl malonate, Meldrum's acid, ethyl acetoacetate or malonic acid, or cyanoacetic acid. [1] Z−CHRR', for instance nitromethane. where Z is an electron withdrawing group. Z must be powerful enough to facilitate deprotonation to the enolate ion even ...
When necessary, the position of the hydroxyl group is indicated by a number between the alkane name and the -ol: propan-1-ol for CH 3 CH 2 CH 2 OH, propan-2-ol for CH 3 CH(OH)CH 3. If a higher priority group is present (such as an aldehyde , ketone , or carboxylic acid ), then the prefix hydroxy- is used, [ 19 ] e.g., as in 1-hydroxy-2 ...
To manufacture anhydrous sodium acetate industrially, the Niacet Process is used. Sodium metal ingots are extruded through a die to form a ribbon of sodium metal, usually under an inert gas atmosphere such as N 2 then immersed in anhydrous acetic acid. 2 CH 3 COOH + 2 Na →2 CH 3 COONa + H 2. The hydrogen gas is normally a valuable byproduct.
The industrial synthesis of acetaldehyde (Wacker process) proceeds via the intermediacy of a vinyl alcohol complex. [4] The uncatalyzed keto–enol tautomerism by a 1,3-hydrogen migration is forbidden by the Woodward–Hoffmann rules and therefore has a high activation barrier and is not a significant pathway at or near room temperature ...