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A closely related property of a substance is the heat capacity per mole of atoms, or atom-molar heat capacity, in which the heat capacity of the sample is divided by the number of moles of atoms instead of moles of molecules. So, for example, the atom-molar heat capacity of water is 1/3 of its molar heat capacity, namely 25.3 J⋅K −1 ⋅mol ...
Von Mayer also published a numerical value for mechanical equivalent of heat in 1845 but his experimental method wasn't as convincing. Though a standardised value of 4.1860 J·cal −1 was established in the early 20th century, in the 1920s, it was ultimately realised that the constant is simply the specific heat of water, a quantity that ...
Mechanical equivalent of heat; ... is that the value of the expression in the parenthesis shall be a minimum. ... energy that accompanies the formation of 1 mole of ...
Numerical values of these thermodynamic properties are collected as tables or are calculated from thermodynamic datafiles. Data is expressed as temperature-dependent values for one mole of substance at the standard pressure of 101.325 kPa (1 atm), or 100 kPa (1 bar).
Mechanical equivalent of heat; Motive power; ... the molar heat capacity (heat capacity per mole), ... The above value of 1.4 is highly consistent with the measured ...
An equivalent statement of the Dulong–Petit law in modern terms is that, regardless of the nature of the substance, the specific heat capacity c of a solid element (measured in joule per kelvin per kilogram) is equal to 3R/M, where R is the gas constant (measured in joule per kelvin per mole) and M is the molar mass (measured in kilogram per mole).
A is the first virial coefficient, which has a constant value of 1 and makes the statement that when volume is large, all fluids behave like ideal gases. The second virial coefficient B corresponds to interactions between pairs of molecules, C to triplets, and so on.
The number of particles in a mole is the Avogadro number (symbol N 0) and the numerical value of the Avogadro constant (symbol N A) expressed in mol −1. [1] The SI value of the mole was chosen on the basis of the historical definition of the mole as the amount of substance that corresponds to the number of atoms in 12 grams of 12 C, [1] which ...