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‡ Second column of table indicates solubility at each given temperature in volume of CO 2 as it would be measured at 101.3 kPa and 0 °C per volume of water. The solubility is given for "pure water", i.e., water which contain only CO 2. This water is going to be acidic. For example, at 25 °C the pH of 3.9 is expected (see carbonic acid).
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The concentrations of carbon dioxide in the atmosphere are expressed as parts per million by volume (abbreviated as ppmv, or ppm(v), or just ppm). To convert from the usual ppmv units to ppm mass (abbreviated as ppmm, or ppm(m)), multiply by the ratio of the molar mass of CO 2 to that of air, i.e. times 1.52 (44.01 divided by 28.96).
Carbon dioxide is soluble in water and is found in groundwater, lakes, ice caps, and seawater. It is a trace gas in Earth's atmosphere at 421 parts per million (ppm), [a] or about 0.042% (as of May 2022) having risen from pre-industrial levels of 280 ppm or about 0.028%.
Conversely, a body of water with a pCO 2 greater than that of the atmosphere effluxes carbon dioxide. [4] [5] pCO 2 is additionally affected by water temperature and salinity. Carbon dioxide is less soluble in warmer water than cooler water, so hot water will exhibit a larger pCO 2 than cold water with the same concentration of carbon dioxide.
Similarly, carbon dioxide absorption bands occur around 1400, 1600 and 2000 nm, [27] but its presence in the Earth's atmosphere accounts for just 26% of the greenhouse effect. [25] Carbon dioxide gas absorbs energy in some small segments of the thermal infrared spectrum that water vapor misses.
A few examples of the major greenhouse gases are water, carbon dioxide, methane, nitrous oxide, ozone, and CFCs. These gases can absorb infrared radiation from the Earth's surface as it passes through the atmosphere. The most influential greenhouse gas is water vapor. It frequently occurs in high concentrations, may transition to and from an ...
If a gaseous emission sample is analyzed and found to contain water vapor and a pollutant concentration of say 40 ppmv, then 40 ppmv should be designated as the "wet basis" pollutant concentration. The following equation can be used to correct the measured "wet basis" concentration to a " dry basis " concentration: [ 3 ]