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The carbon–fluorine bond of the smaller molecules is formed in three principal ways: Fluorine replaces a halogen or hydrogen, or adds across a multiple bond. The direct reaction of hydrocarbons with fluorine gas can be dangerously reactive, so the temperature may need to be lowered even to −150 °C (−240 °F). [115] "
Fluorine is a chemical element; it has symbol F and atomic number 9. It is the lightest halogen [note 1] and exists at standard conditions as pale yellow diatomic gas. Fluorine is extremely reactive as it reacts with all other elements except for the light inert gases. It is highly toxic.
Bromine is a weaker halogenating agent than both fluorine and chlorine, while iodine is the least reactive of them all. The facility of dehydrohalogenation follows the reverse trend: iodine is most easily removed from organic compounds, and organofluorine compounds are highly stable.
HF is a reactive solvent in the electrochemical fluorination of organic compounds. In this approach, HF is oxidized in the presence of a hydrocarbon and the fluorine replaces C–H bonds with C–F bonds. Perfluorinated carboxylic acids and sulfonic acids are produced in this way. [15]
Fluorine is the thirteenth most abundant element on Earth and the 24th most abundant element in the universe. It is the most electronegative element and it is highly reactive. Thus, it is rarely found in its elemental state, although elemental fluorine has been identified in certain geochemical contexts. [3]
Fluorine is so rare because it is not a product of the usual nuclear fusion processes in stars. And any created fluorine within stars is rapidly eliminated through strong nuclear fusion reactions—either with hydrogen to form oxygen and helium, or with helium to make neon and hydrogen.
Fluorine, in the form of fluoride, is considered to be a micronutrient for human health, necessary to prevent dental cavities, and to promote healthy bone growth. [28] The tea plant (Camellia sinensis L.) is a known accumulator of fluorine compounds, released upon forming infusions such as the common beverage. The fluorine compounds decompose ...
To understand why the reactivity changes occur, we need to consider the orbital overlaps occurring in each. The valence orbitals of fluorine are the 2p orbitals which is the same for carbon - hence they will be very close in energy and orbital overlap will be favourable.