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  2. Metallic bonding - Wikipedia

    en.wikipedia.org/wiki/Metallic_bonding

    The strong bonding of metals in liquid form demonstrates that the energy of a metallic bond is not highly dependent on the direction of the bond; this lack of bond directionality is a direct consequence of electron delocalization, and is best understood in contrast to the directional bonding of covalent bonds.

  3. Bonding in solids - Wikipedia

    en.wikipedia.org/wiki/Bonding_in_solids

    Covalent bonding corresponds to sharing of a pair of electrons between two atoms of essentially equal electronegativity (for example, C–C and C–H bonds in aliphatic hydrocarbons). As bonds become more polar, they become increasingly ionic in character. Metal oxides vary along the iono-covalent spectrum. [4]

  4. Metal–metal bond - Wikipedia

    en.wikipedia.org/wiki/Metalmetal_bond

    Mn 2 (CO) 10 is a simple and clear case of a metal-metal bond because no other atoms tie the two Mn atoms together. When several metals are linked by metal-metal bonds, the compound or ion is called a metal cluster. Many metal clusters contain several unsupported M–M bonds. Some examples are M 3 (CO) 12 (M = Ru, Os) and Ir 4 (CO) 12.

  5. Ligand - Wikipedia

    en.wikipedia.org/wiki/Ligand

    Some ligands can bond to a metal center through the same atom but with a different number of lone pairs. The bond order of the metal ligand bond can be in part distinguished through the metal ligand bond angle (M−X−R). This bond angle is often referred to as being linear or bent with further discussion concerning the degree to which the ...

  6. Chemical bond - Wikipedia

    en.wikipedia.org/wiki/Chemical_bond

    The bond results because the metal atoms become somewhat positively charged due to loss of their electrons while the electrons remain attracted to many atoms, without being part of any given atom. Metallic bonding may be seen as an extreme example of delocalization of electrons over a large system of covalent bonds, in which every atom ...

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  8. Sandwich compound - Wikipedia

    en.wikipedia.org/wiki/Sandwich_compound

    Because the metal is usually situated between the two rings, it is said to be "sandwiched". A special class of sandwich complexes are the metallocenes . The term sandwich compound was introduced in organometallic nomenclature in 1956 in a report by J. D. Dunitz, L. E. Orgel and R. A. Rich, who confirmed the structure of ferrocene by X-ray ...

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