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This allows the development of an equilibrium between the liquid and the air volume. The ignition source is directed into the cup at regular intervals with simultaneous interruption of stirring. The test concludes upon observation of a flash that spreads throughout the inside of the cup. The corresponding temperature is the liquid's flash point.
Closed cup testers normally give lower values for the flash point than open cup (typically 5–10 °C or 9–18 °F lower) and are a better approximation to the temperature at which the vapour pressure reaches the lower flammable limit. In addition to the Penskey-Martens flash point testers, other non-equilibrial testers include TAG and Abel ...
The Cleveland open-cup method is one of three main methods in chemistry for determining the flash point of a petroleum product using a Cleveland open-cup apparatus, also known as a Cleveland open-cup tester. [1] First, the test cup of the apparatus (usually brass) is filled to a certain level with a portion of the product.
A flammable liquid is a liquid having a flash point of not more than 60 °C (140 °F), or any material in a liquid phase with a flash point at or above 37.8 °C (100 °F) that is intentionally heated and offered for transportation or transported at or above its flash point in a bulk packaging. The following exceptions apply:
The Abel test is a method developed by the British chemist Frederick Abel (1827–1902) to determine the flash point of a given sample of petroleum in order to ascertain the temperature at which it could safely be stored or used. [1]
Closed cup testers normally give lower values for the flash point than open cup (typically 5–10 °C (41–50 °F)) In this context, the temperature is being compared (a temperature difference) rather than converted (to a thermometric temperature), and as such "5–10 °C" equals "9–18 °F", rather than the stated value of "41–50 °F".
If the throttling valve or device is located at the entry into a pressure vessel so that the flash evaporation occurs within the vessel, then the vessel is often referred to as a flash drum. [1] [2] If the saturated liquid is a single-component liquid (for example, propane or liquid ammonia), a part of the liquid immediately "flashes" into vapor.
Most tables of material properties will only list material flash points. In general, the fire point can be assumed to be about 10 °C higher than the flash point, [2] although this is no substitute for testing if the fire point is safety critical. [2] Testing of the fire point is done by open cup apparatus. [2] [3]