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As a chemical warfare agent, chlorine was first used in World War I as a poison gas weapon. In the form of chloride ions, chlorine is necessary to all known species of life. Other types of chlorine compounds are rare in living organisms, and artificially produced chlorinated organics range from inert to toxic.
A chloride ion is a structural component of some proteins; for example, it is present in the amylase enzyme. For these roles, chloride is one of the essential dietary mineral (listed by its element name chlorine). Serum chloride levels are mainly regulated by the kidneys through a variety of transporters that are present along the nephron. [19]
Hydrogen chloride is produced by combining chlorine and hydrogen: Cl 2 + H 2 → 2 HCl. As the reaction is exothermic, the installation is called an HCl oven or HCl burner. The resulting hydrogen chloride gas is absorbed in deionized water, resulting in chemically pure hydrochloric acid. This reaction can give a very pure product, e.g. for use ...
At the anode (A), chloride (Cl −) is oxidized to chlorine. The ion-selective membrane (B) allows the counterion Na+ to freely flow across, but prevents anions such as hydroxide (OH −) and chloride from diffusing across. At the cathode (C), water is reduced to hydroxide and hydrogen gas. The net process is the electrolysis of an aqueous ...
Hypochlorite salts formed by the reaction between chlorine and alkali and alkaline earth metal hydroxides. The reaction is performed at close to room temperature to suppress the formation of chlorates. This process is widely used for the industrial production of sodium hypochlorite (NaClO) and calcium hypochlorite (Ca(ClO) 2).
The industrial-scale synthesis for sodium chlorate starts from an aqueous sodium chloride solution (brine) rather than chlorine gas. If the electrolysis equipment allows for the mixing of the chlorine and the sodium hydroxide , then the disproportionation reaction described above occurs.
The chlorite ion adopts a bent molecular geometry, due to the effects of the lone pairs on the chlorine atom, with an O–Cl–O bond angle of 111° and Cl–O bond lengths of 156 pm. [1] Chlorite is the strongest oxidiser of the chlorine oxyanions on the basis of standard half cell potentials.
In this process, the feedstock is treated at 1000 °C with carbon and chlorine gas, giving titanium tetrachloride. Typical is the conversion starting from the ore ilmenite: [2] 2 FeTiO 3 + 7 Cl 2 + 6 C → 2 TiCl 4 + 2 FeCl 3 + 6 CO. The process is a variant of a carbothermic reaction, which exploits the reducing power of carbon.