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SO 2 + NaOH → NaHSO 3 SO 2 + NaHCO 3 → NaHSO 3 + CO 2. Attempts to crystallize the product yield sodium metabisulfite (also called sodium disulfite), Na 2 S 2 O 5. [6] Upon dissolution of the metabisulfite in water, bisulfite is regenerated: Na 2 S 2 O 5 + H 2 O → 2 Na + + 2 HSO 3 −. Sodium bisulfite is formed during the Wellman-Lord ...
The various crystalline forms of Fe 2 (SO 4) 3 (H 2 O) n are well-defined, often by X-ray crystallography. The nature of the aqueous solutions is often less certain, but aquo-hydroxo complexes such as [Fe(H 2 O) 6] 3+ and [Fe(H 2 O) 5 (OH)] 2+ are often assumed. [4] Regardless, all such solids and solutions feature ferric ions, each with five ...
Thermolysis of iron(II) sulfate begins at about 680 °C (1,256 °F). 2 FeSO 4 Fe 2 O 3 + SO 2 + SO 3. Like other iron(II) salts, iron(II) sulfate is a reducing agent. For example, it reduces nitric acid to nitrogen monoxide and chlorine to chloride: 6 FeSO 4 + 3 H 2 SO 4 + 2 HNO 3 → 3 Fe 2 (SO 4) 3 + 4 H 2 O + 2 NO 6 FeSO 4 + 3 Cl 2 → 2 Fe ...
Sodium bisulfate, also known as sodium hydrogen sulfate, [a] is the sodium salt of the bisulfate anion, with the molecular formula NaHSO 4.Sodium bisulfate is an acid salt formed by partial neutralization of sulfuric acid by an equivalent of sodium base, typically in the form of either sodium hydroxide (lye) or sodium chloride (table salt).
When conducted in warm water, Na 2 SO 3 initially precipitates as a white solid. With more SO 2, the solid dissolves to give the disulfite, which crystallizes upon cooling. [2] SO 2 + 2 NaOH → Na 2 SO 3 + H 2 O. Sodium sulfite is made industrially by treating sulfur dioxide with a solution of sodium carbonate. [3] The overall reaction is:
Ammonium iron(II) sulfate, or Mohr's salt, is the inorganic compound with the formula (NH 4) 2 SO 4 ·Fe(SO 4)·6H 2 O.Containing two different cations, Fe 2+ and NH + 4, it is classified as a double salt of ferrous sulfate and ammonium sulfate.
Generally, it employs: either ferrous (Fe II) or ferric (Fe III) salts as the source of iron ions, calcium, sodium hypochlorite (Ca(ClO) 2, NaClO), sodium thiosulfate (Na 2 S 2 O 3) or chlorine (Cl 2) as oxidizing agents and, finally, sodium hydroxide, sodium carbonate (NaOH, NaCO 3) or potassium hydroxide (KOH) to increase the pH of the solution.
2 O 2− 5), also known as disulfite: 2 HSO − 3 ⇌ S 2 O 2− 5 + H 2 O. Because of this equilibrium, anhydrous sodium and potassium salts of bisulfite cannot be obtained. However, there are some reports of anhydrous bisulfites with large counter ions. [4] Structure of disulfite (aka metabisulfite) ion. [5]