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The Cram's rule of asymmetric induction named after Donald J. Cram states In certain non-catalytic reactions that diastereomer will predominate, which could be formed by the approach of the entering group from the least hindered side when the rotational conformation of the C-C bond is such that the double bond is flanked by the two least bulky groups attached to the adjacent asymmetric center. [3]
These induced surface charges create an opposing electric field that exactly cancels the field of the external charge throughout the interior of the metal. Therefore electrostatic induction ensures that the electric field everywhere inside a conductive object is zero. A remaining question is how large the induced charges are.
In Organic chemistry, the inductive effect in a molecule is a local change in the electron density due to electron-withdrawing or electron-donating groups elsewhere in the molecule, resulting in a permanent dipole in a bond. [1] It is present in a σ (sigma) bond, unlike the electromeric effect which is present in a π (pi) bond.
Free-radical reactions depend on one or more relatively weak bonds in a reagent. Under reaction conditions (typically heat or light), some weak bonds homolyse into radicals, which then induce further decomposition in their compatriots before recombination. Different mechanisms typically apply to reagents without such a weak bond.
The induced currents in this ring can't enclose themselves in the ring, and have a very weak field that cannot resist the change of the magnetic flux. In electromagnetism, when charges move along electric field lines work is done on them, whether it involves storing potential energy (negative work) or increasing kinetic energy (positive work).
A molecule with permanent dipole can induce a dipole in a similar neighboring molecule and cause mutual attraction. Debye forces cannot occur between atoms. The forces between induced and permanent dipoles are not as temperature dependent as Keesom interactions because the induced dipole is free to shift and rotate around the polar molecule.
Countercurrent exchange is a mechanism between two flowing bodies flowing in opposite directions to each other, in which there is a transfer of some property, usually heat or some chemical. The flowing bodies can be liquids, gases, or even solid powders, or any combination of those.
In physics, the terms order and disorder designate the presence or absence of some symmetry or correlation in a many-particle system. [citation needed]In condensed matter physics, systems typically are ordered at low temperatures; upon heating, they undergo one or several phase transitions into less ordered states.