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Citric acid is a triprotic acid, with pK a values, extrapolated to zero ionic strength, of 3.128, 4.761, and 6.396 at 25 °C. [21] The pK a of the hydroxyl group has been found, by means of 13 C NMR spectroscopy, to be 14.4. [22] The speciation diagram shows that solutions of citric acid are buffer solutions between about pH 2 and pH 8. In ...
Acid–base extraction is a subclass of liquid–liquid extractions and involves the separation of chemical species from other acidic or basic compounds. [1] It is typically performed during the work-up step following a chemical synthesis to purify crude compounds [2] and results in the product being largely free of acidic or basic impurities.
Add 1 oz (28 g) lime juice (a former ingredient, evidently, that Coca-Cola now denies) or a substitute such as a water solution of citric acid and sodium citrate at lime-juice strength. Mix together 1 ⁄ 4 drachm (0.44 g) orange oil, 1 ⁄ 10 drachm (0.18 g) cassia (Chinese cinnamon) oil, 1 ⁄ 2 drachm (0.89 g) lemon oil, traces of
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McIlvaine buffer is a buffer solution composed of citric acid and disodium hydrogen phosphate, also known as citrate-phosphate buffer.It was introduced in 1921 by the United States agronomist Theodore Clinton McIlvaine (1875–1959) from West Virginia University, and it can be prepared in pH 2.2 to 8 by mixing two stock solutions.
Biological substances can experience leaching themselves, [2] as well as be used for leaching as part of the solvent substance to recover heavy metals. [6] Many plants experience leaching of phenolics, carbohydrates, and amino acids, and can experience as much as 30% mass loss from leaching, [5] just from sources of water such as rain, dew, mist, and fog. [2]
Similarly "spirit(s) of salt" actually meant hydrochloric acid. The concentrated, fuming, 35% acid is still sold under this name in the UK, for use as a drain-cleaning fluid. "Spirit of vinegar" is an antiquated term for glacial acetic acid "Spirit of vitriol" is an antiquated term for sulfuric acid
Extraction in chemistry is a separation process consisting of the separation of a substance from a matrix. The distribution of a solute between two phases is an equilibrium condition described by partition theory.