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The grand canonical partition function applies to a grand canonical ensemble, in which the system can exchange both heat and particles with the environment, at fixed temperature, volume, and chemical potential. Other types of partition functions can be defined for different circumstances; see partition function (mathematics) for
The partition function or configuration integral, as used in probability theory, information theory and dynamical systems, is a generalization of the definition of a partition function in statistical mechanics. It is a special case of a normalizing constant in probability theory, for the Boltzmann distribution.
A partition in which no part occurs more than once is called strict, or is said to be a partition into distinct parts. The function q(n) gives the number of these strict partitions of the given sum n. For example, q(3) = 2 because the partitions 3 and 1 + 2 are strict, while the third partition 1 + 1 + 1 of 3 has repeated parts.
The only partition of zero is the empty sum, having no parts. The order-dependent composition 1 + 3 is the same partition as 3 + 1, and the two distinct compositions 1 + 2 + 1 and 1 + 1 + 2 represent the same partition as 2 + 1 + 1. An individual summand in a partition is called a part. The number of partitions of n is given by the partition ...
The partition function or configuration integral, as used in probability theory, information science and dynamical systems, is an abstraction of the definition of a partition function in statistical mechanics. In statistical mechanics, the partition function, Z, encodes the statistical properties of a system in thermodynamic equilibrium.
In statistical mechanics, the translational partition function, is that part of the partition function resulting from the movement (translation) of the center of mass. For a single atom or molecule in a low pressure gas, neglecting the interactions of molecules , the canonical ensemble q T {\displaystyle q_{T}} can be approximated by: [ 1 ]
In quantum field theory, partition functions are generating functionals for correlation functions, making them key objects of study in the path integral formalism. They are the imaginary time versions of statistical mechanics partition functions , giving rise to a close connection between these two areas of physics.
The partition function for the -ensemble can be derived from statistical mechanics by beginning with a system of identical atoms described by a Hamiltonian of the form / + and contained within a box of volume =.