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Potassium chloride (KCl, or potassium salt) is a metal halide salt composed of potassium and chlorine. It is odorless and has a white or colorless vitreous crystal appearance. The solid dissolves readily in water, and its solutions have a salt -like taste.
Potassium hypochlorite is produced by the disproportionation reaction of chlorine with a solution of potassium hydroxide: [2] Cl 2 + 2 KOH → KCl + KOCl + H 2 O. This is the traditional method, first used by Claude Louis Berthollet in 1789. [3] Another production method is electrolysis of potassium chloride solution.
With further heating, potassium perchlorate decomposes to potassium chloride and oxygen: KClO 4 → KCl + 2 O 2. The safe performance of this reaction requires very pure reagents and careful temperature control. Molten potassium chlorate is an extremely powerful oxidizer and spontaneously reacts with many common materials such as sugar.
Chlorine can also be produced by the electrolysis of a solution of potassium chloride, in which case the co-products are hydrogen and caustic potash (potassium hydroxide). There are three industrial methods for the extraction of chlorine by electrolysis of chloride solutions, all proceeding according to the following equations:
The only variable in this equation is the activity (or concentration) of the chloride anion. But since the inner solution is saturated with potassium chloride, this activity is fixed by the solubility of potassium chloride, which is: 342 g/L / 74.5513 g/mol = 4.587 M @ 20 °C.
Aluminium powder and potassium perchlorate are the only two components of the pyrotechnic industry standard flash powder. It provides a great balance of stability and power, and is the composition used in most commercial exploding fireworks. The balanced equation for the reaction is:- 3 KClO 4 + 8 Al → 3 KCl + 4 Al 2 O 3
Because potassium concentrations are very low, they usually have little effect on the calculated gap. Therefore, omission of potassium has become widely accepted. This leaves the following equation: = [Na +] - ([Cl −] + [HCO − 3]) Normal AG = 8-16 mEq/L Expressed in words, the equation is: Anion Gap = sodium - (chloride + bicarbonate)
Potassium chlorite is a potassium salt of chlorous acid (HClO 2) having a chemical formula KClO 2. It exists as white powder and its annhydrous form easily undergoes decomposition in presence of heat or radiation (especially gamma rays ).