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2-Hydroxyestradiol is a catechol estrogen and in this regard bears some structural resemblance to the catecholamines dopamine, norepinephrine (noradrenaline), and epinephrine (adrenaline). [6] In accordance, 2-hydroxyestradiol has been found to interact with catecholamine systems. [6]
Through the action of CYP1A1, CYP1A2, CYP2C8, and the CYP3A isoforms, 16α-hydroxyestradiol (16α-OHE 2), also known as estriol, is produced in abundance during pregnancy. 16α-OHE 2 can be dehydrogenated to 16α-hydroxyestrone (16α-OHE 1), a metabolite that has been shown to bind covalently to the estrogen receptor via Schiff base formation. [11]
2-Hydroxyestrone (2-OHE1), also known as estra-1,3,5(10)-trien-2,3-diol-17-one, is an endogenous, naturally occurring catechol estrogen and a major metabolite of estrone and estradiol. [ 1 ] [ 2 ] [ 3 ] It is formed irreversibly from estrone in the liver and to a lesser extent in other tissues via 2- hydroxylation mediated by cytochrome P450 ...
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Tryptophan hydroxylase (TPH) is an enzyme (EC 1.14.16.4) involved in the synthesis of the monoamine neurotransmitter serotonin. Tyrosine hydroxylase , phenylalanine hydroxylase , and tryptophan hydroxylase together constitute the family of biopterin-dependent aromatic amino acid hydroxylases .
5-HTP is produced from the amino acid tryptophan through the action of the enzyme tryptophan hydroxylase. Tryptophan hydroxylase is one of the biopterin-dependent aromatic amino acid hydroxylases. Production of 5-HTP is the rate-limiting step in 5-HT (serotonin) synthesis. 5-HTP is normally rapidly converted to 5-HT by amino acid decarboxylase. [1]
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