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The rubidium content in minerals is often calculated and quoted in terms of Rb 2 O. In reality, the rubidium is typically present as a component of (actually, an impurity in) silicate or aluminosilicate. A major source of rubidium is lepidolite, KLi 2 Al(Al,Si) 3 O 10 (F,OH) 2, wherein Rb sometimes replaces K. Rb 2 O is a yellow colored solid.
Rubidium sesquioxide is a chemical compound with the formula Rb 2 O 3 or more accurately Rb 4 O 6.In terms of oxidation states, Rubidium in this compound has a nominal charge of +1, and the oxygen is a mixed peroxide (O 2− 2) and superoxide (O − 2) for a structural formula of (Rb +) 4 (O − 2) 2 (O 2− 2). [4]
Rubidium is a chemical element; it has symbol Rb and atomic number 37. It is a very soft, whitish-grey solid in the alkali metal group, similar to potassium and caesium. [9] Rubidium is the first alkali metal in the group to have a density higher than water.
It can be created by slowly exposing elemental rubidium to oxygen gas: [3] Rb(s) + O 2 (g) → RbO 2 (s) Like other alkali metal hyperoxides, crystals can also be grown in liquid ammonia. [4] Between 280 and 360 °C, Rubidium superoxide will decompose, leaving not rubidium sesquioxide (Rb 2 O 3), but rather rubidium peroxide (Rb 2 O 2). [3]
Similar to potassium permanganate, the two-step decomposition of rubidium permanganate leads to the formation of rubidium manganate intermediates. It breaks down into manganese dioxide, rubidium oxide and oxygen. [4] The decomposition temperature is between 200 and 300 °C. [7] Drift-away oxygen caused an 8% mass loss in the product. [7]
Rubidium perchlorate can be obtained through the careful heating of a rubidium chlorate solution, leading to a disproportionation reaction with the release of oxygen gas: [3] 2 RbClO 3 → RbClO 4 + RbCl + O 2. When heated, it decomposes into the chloride and oxygen: [4] RbClO 4 → RbCl + 2 O 2. It has two polymorphs.
In addition to the neutral rubidium oxalate Rb 2 C 2 O 4, there is also an acidic salt, rubidium hydrogen oxalate with the formula RbHC 2 O 4, which is isomorphic to potassium hydrogen oxalate KHC 2 O 4 [10] and forms monoclinic crystals, [11] and an acidic dioxalate with the formula RbHC 2 O 4 ·H 2 C 2 O 4, which exists as a dihydrate, has a ...
Chemical formula. O 2 Rb 2: Molar mass: 202.934 g·mol −1 Appearance colourless solid [1] ... Rubidium peroxide is rubidium's peroxide with the chemical formula Rb ...