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Example Bjerrum plot: Change in carbonate system of seawater from ocean acidification.. A Bjerrum plot (named after Niels Bjerrum), sometimes also known as a Sillén diagram (after Lars Gunnar Sillén), or a Hägg diagram (after Gunnar Hägg) [1] is a graph of the concentrations of the different species of a polyprotic acid in a solution, as a function of pH, [2] when the solution is at ...
This process is known as thermohaline circulation. In the Earth's polar regions ocean water gets very cold, forming sea ice. As a consequence the surrounding seawater gets saltier, because when sea ice forms, the salt is left behind. As the seawater gets saltier, its density increases, and it starts to sink.
II) An equilibrium between seawater and planktonic nutrient pools is maintained through biotic feedback mechanisms. [1] [3] Redfield proposed a thermostat like scenario in which the activities of nitrogen fixers and denitrifiers keep the nitrate to phosphate ratio in the seawater near the requirements in the protoplasm. [4]
The balance of these carbonate species (which ultimately affects the solubility of carbon dioxide), is dependent on factors such as pH, as shown in a Bjerrum plot.In seawater this is regulated by the charge balance of a number of positive (e.g. Na +, K +, Mg 2+, Ca 2+) and negative (e.g. CO 3 2− itself, Cl −, SO 4 2−, Br −) ions.
The average density at the surface is 1.025 kg/L. Seawater is denser than both fresh water and pure water (density 1.0 kg/L at 4 °C (39 °F)) because the dissolved salts increase the mass by a larger proportion than the volume. The freezing point of seawater decreases as salt concentration increases.
Spreading rates on mid-ocean ridges vary between 10 and 200 mm/yr. Rapid spreading rates cause increased basalt reactions with seawater. The magnesium / calcium ratio will be lower because more magnesium ions are being removed from seawater and consumed by the rock, and more calcium ions are being removed from the rock and released to seawater.
Phosphorus concentration in the nodules ranges from 2.5 to 7 times the value of the surrounding soil matrix. [2] Microbes in the soil can utilize the nutrient enrichment on the surface of nodules coupled with their redox potential to fuel their metabolic pathways and release the once immobile phosphorus. [ 2 ]
Evaporation of groundwater increases the chemical concentration of water. Or intrusion of seawater increases the chemical concentration of water. Water is too saline to be drinkable. [47] Saline 10000-36000 Similar to seawater. Strong evaporation of groundwater or fully mixing with seawater. Hyper-Saline 36000-100000