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II) An equilibrium between seawater and planktonic nutrient pools is maintained through biotic feedback mechanisms. [1] [3] Redfield proposed a thermostat like scenario in which the activities of nitrogen fixers and denitrifiers keep the nitrate to phosphate ratio in the seawater near the requirements in the protoplasm. [4]
ca 2+ + 2hco 3 − → co 2 + h 2 o + caco 3 [112] The relationship between dissolved calcium and calcium carbonate is affected greatly by the levels of carbon dioxide (CO 2 ) in the atmosphere. Increased carbon dioxide leads to more bicarbonate in the ocean according to the following equation:
Example Bjerrum plot: Change in carbonate system of seawater from ocean acidification.. A Bjerrum plot (named after Niels Bjerrum), sometimes also known as a Sillén diagram (after Lars Gunnar Sillén), or a Hägg diagram (after Gunnar Hägg) [1] is a graph of the concentrations of the different species of a polyprotic acid in a solution, as a function of pH, [2] when the solution is at ...
The balance of these carbonate species (which ultimately affects the solubility of carbon dioxide), is dependent on factors such as pH, as shown in a Bjerrum plot.In seawater this is regulated by the charge balance of a number of positive (e.g. Na +, K +, Mg 2+, Ca 2+) and negative (e.g. CO 3 2− itself, Cl −, SO 4 2−, Br −) ions.
Of crucial importance for paleoclimatology is the observation that an increase in salinity will thus reduce the solubility of carbon dioxide in the oceans. Since there is thought to have been a 120 m depression in sea level at the last glacial maximum due to the extensive formation of ice sheets (which are solely freshwater), this represents a ...
Spreading rates on mid-ocean ridges vary between 10 and 200 mm/yr. Rapid spreading rates cause increased basalt reactions with seawater. The magnesium / calcium ratio will be lower because more magnesium ions are being removed from seawater and consumed by the rock, and more calcium ions are being removed from the rock and released to seawater.
Seawater, or sea water, is water from a sea or ocean. On average, seawater in the world's oceans has a salinity of about 3.5% (35 g/L, 35 ppt, 600 mM). This means that every kilogram (roughly one liter by volume) of seawater has approximately 35 grams (1.2 oz) of dissolved salts (predominantly sodium ( Na +
As CO 2 concentrations in seawater rise, a decrease in pH and a reduction in carbonate ion concentrations in seawater follows. And, since calcification is a source of CO 2 to the surrounding water, decreased rates of global calcification would inversely affect the rate of atmospheric CO 2 absorption, perpetuating these effects. [ 11 ]