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The term molality is formed in analogy to molarity which is the molar concentration of a solution. The earliest known use of the intensive property molality and of its adjectival unit, the now-deprecated molal, appears to have been published by G. N. Lewis and M. Randall in the 1923 publication of Thermodynamics and the Free Energies of Chemical Substances. [3]
Molar concentration or molarity is most commonly expressed in units of moles of solute per litre of solution. [1] For use in broader applications, it is defined as amount of substance of solute per unit volume of solution, or per unit volume available to the species, represented by lowercase : [2]
For example, a 1 mol/L solution of glucose is 1 osmol/L. [2] Multiple compounds may contribute to the osmolarity of a solution. For example, a 3 Osm solution might consist of 3 moles glucose, or 1.5 moles NaCl, or 1 mole glucose + 1 mole NaCl, or 2 moles glucose + 0.5 mole NaCl, or any other such combination. [2]
For example, following the common practice in titration, it may be expressed as moles of solute per litre of solution (mol/L), the molarity of the latter. In more specialized contexts the solubility may be given by the mole fraction (moles of solute per total moles of solute plus solvent) or by the mass fraction at equilibrium (mass of solute ...
The solutions on the left are more dilute, compared to the more concentrated solutions on the right. Often in informal, non-technical language, concentration is described in a qualitative way, through the use of adjectives such as "dilute" for solutions of relatively low concentration and "concentrated" for solutions of relatively high ...
The molar ionic strength, I, of a solution is a function of the concentration of all ions present in that solution. [3]= = where one half is because we are including both cations and anions, c i is the molar concentration of ion i (M, mol/L), z i is the charge number of that ion, and the sum is taken over all ions in the solution.
The number ratio can be related to the various units for concentration of a solution such as molarity, molality, normality (chemistry), etc. The assumption that solution properties are independent of nature of solute particles is exact only for ideal solutions , which are solutions that exhibit thermodynamic properties analogous to those of an ...
Normality is defined as the number of gram or mole equivalents of solute present in one liter of solution.The SI unit of normality is equivalents per liter (Eq/L). = where N is normality, m sol is the mass of solute in grams, EW sol is the equivalent weight of solute, and V soln is the volume of the entire solution in liters.