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The chemical compound 1,2-dichloroethane, commonly known as ethylene dichloride (EDC), is a chlorinated hydrocarbon. It is a colourless liquid with a chloroform -like odour . The most common use of 1,2-dichloroethane is in the production of vinyl chloride , which is used to make polyvinyl chloride (PVC) pipes, furniture and automobile ...
Oxychlorination is employed in the conversion of ethylene into vinyl chloride. In the first step in this process, ethylene undergoes oxychlorination to give ethylene chloride: CH 2 =CH 2 + 2 HCl + ½ O 2 → ClCH 2 CH 2 Cl + H 2 O. Oxychlorination is of special importance in the making of 1,2-dichloroethane, which is then converted into vinyl ...
Non condensible gases and remaining chlorine gas are vented off as part of the pressure control of the liquefaction systems. These gases are routed to a gas scrubber, producing sodium hypochlorite, or used in the production of hydrochloric acid (by combustion with hydrogen) or ethylene dichloride (by reaction with ethylene).
Countercurrent distribution is a separation process that is founded on the principles of liquid–liquid extraction where a chemical compound is distributed (partitioned) between two immiscible liquid phases (oil and water for example) according to its relative solubility in the two phases.
1,2-Dichloroethane, ClCH 2 CH 2 Cl (also known as ethylene dichloride, EDC), can be prepared by halogenation of ethane or ethylene, inexpensive starting materials. EDC thermally converts into vinyl chloride and anhydrous HCl. This production method has become the major route to vinyl chloride since the late 1950s. [2]
Chloroethane is produced by hydrochlorination of ethylene: [11]. C 2 H 4 + HCl → C 2 H 5 Cl. At various times in the past, chloroethane has also been produced from ethanol and hydrochloric acid, from ethane and chlorine, or from ethanol and phosphorus trichloride, but these routes are no longer economical.
On an industrial scale, base-promoted dehydrohalogenations as described above are disfavored. The disposal of the alkali halide salt is problematic. Instead thermally-induced dehydrohalogenations are preferred. One example is provided by the production of vinyl chloride by heating 1,2-dichloroethane: [3] CH 2 Cl-CH 2 Cl → CH 2 =CHCl + HCl
Two extremes of the thermal cracking in terms of the product range are represented by the high-temperature process called "steam cracking" or pyrolysis (ca. 750 °C to 900 °C or higher) which produces valuable ethylene and other feedstocks for the petrochemical industry, and the milder-temperature delayed coking (ca. 500 °C) which can produce ...