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Lead perchlorate trihydrate is produced by the reaction of lead(II) oxide, lead carbonate, or lead nitrate by perchloric acid: . Pb(NO 3) 2 + HClO 4 → Pb(ClO 4) 2 + HNO 3. The excess perchloric acid was removed by first heating the solution to 125 °C, then heating it under moist air at 160 °C to remove the perchloric acid by converting the acid to the dihydrate.
Chlorate is the common name of the ClO − 3 anion, whose chlorine atom is in the +5 oxidation state.The term can also refer to chemical compounds containing this anion, with chlorates being the salts of chloric acid.
Thus while carbon tetrachloride is a stable compound, with lead the oxidation state +2 is favored and PbCl 4 quickly becomes PbCl 2. Indeed, the inert pair effect causes lead to favor its +2 oxidation state: Pb atom loses all its outermost p electrons and ends up with a stable, filled s subshell. [7]
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
3 Pb 2 CO 3 (OH) 2 + O 2 → 2 Pb 3 O 4 + 3 CO 2 + 3 H 2 O. In solution, lead(II,IV) oxide can be prepared by reaction of potassium plumbate with lead(II) acetate, yielding yellow insoluble lead(II,IV) oxide monohydrate Pb 3 O 4 ·H 2 O, which can be turned into the anhydrous form by gentle heating: K 2 PbO 3 + 2 Pb(OCOCH 3) 2 + H 2 O → Pb 3 ...
In the gas phase, PbCl 2 molecules have a bent structure with the Cl–Pb–Cl angle being 98° and each Pb–-Cl bond distance being 2.44 Å. [7] Such PbCl 2 is emitted from internal combustion engines that use ethylene chloride-tetraethyllead additives for antiknock purposes.
Lead (82 Pb) has four observationally stable isotopes: 204 Pb, 206 Pb, 207 Pb, 208 Pb. Lead-204 is entirely a primordial nuclide and is not a radiogenic nuclide.The three isotopes lead-206, lead-207, and lead-208 represent the ends of three decay chains: the uranium series (or radium series), the actinium series, and the thorium series, respectively; a fourth decay chain, the neptunium series ...
It dissolves in nitric acid with the evolution of nitric oxide gas to form dissolved Pb(NO 3) 2. 3 Pb + 8 H + + 8 NO − 3 → 3 Pb 2+ + 6 NO − 3 + 2 NO + 4 H 2 O. When heated with nitrates of alkali metals, metallic lead oxidizes to form PbO (also known as litharge), leaving the corresponding alkali nitrite. PbO is representative of lead's ...