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In organic chemistry, an allyl group is a substituent with the structural formula −CH 2 −HC=CH 2. It consists of a methylene bridge ( −CH 2 − ) attached to a vinyl group ( −CH=CH 2 ). [ 1 ] [ 2 ] The name is derived from the scientific name for garlic , Allium sativum .
Allyl alcohol is converted mainly to glycidol, which is a chemical intermediate in the synthesis of glycerol, glycidyl ethers, esters, and amines. Also, a variety of polymerizable esters are prepared from allyl alcohol, e.g. diallyl phthalate. [5] Allyl alcohol has herbicidal activity and can be used as a weed eradicant [9]) and fungicide. [8]
Transition-metal allyl complexes are coordination complexes with allyl and its derivatives as ligands. Allyl is the radical with the connectivity CH 2 CHCH 2 , although as a ligand it is usually viewed as an allyl anion CH 2 =CH−CH 2 − , which is usually described as two equivalent resonance structures.
Pages in category "Allyl compounds" The following 114 pages are in this category, out of 114 total. This list may not reflect recent changes. 0–9. 2C-AL; 2C-T-16; A.
Allyl isothiocyanate (AITC) is a naturally occurring unsaturated isothiocyanate. The colorless oil is responsible for the pungent taste of cruciferous vegetables such as mustard , radish , horseradish , and wasabi .
Allyl glycidyl ether is an organic compound used in adhesives and sealants and as a monomer for polymerization reactions. It is formally the condensation product of allyl alcohol and glycidol via an ether linkage.
Allyl chloride is the organic compound with the formula C H 2 =CHCH 2 Cl. This colorless liquid is insoluble in water but soluble in common organic solvents. It is mainly converted to epichlorohydrin , used in the production of plastics.
Allyl halides are organic halides containing an allyl group. Allyl halides include: Allyl chloride; Allyl bromide; Allyl iodide; Allyl fluoride [Wikidata] See also.