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Nickel(II) sulfate, or just nickel sulfate, usually refers to the inorganic compound with the formula NiSO 4 (H 2 O) 6. This highly soluble turquoise coloured salt is a common source of the Ni 2+ ion for electroplating. Approximately 40,000 tonnes were produced in 2005. [1]
Nickel(II) sulfate can crystallise with six water molecules yielding Retgersite or with seven making Morenosite which is isomorphic to Epsom salts. These contain the hexaquanickel(II) ion. [ 1 ] There is also an anhydrous form, a dihydrate and a tetrahydrate, the last two crystallised from sulfuric acid.
Nickel compounds are chemical compounds containing the element nickel which is a member of the group 10 of the periodic table. Most compounds in the group have an oxidation state of +2. Nickel is classified as a transition metal with nickel(II) having much chemical behaviour in common with iron(II) and cobalt(II).
Potassium Nickel Sulfate Hexahydrate [14] used as UV filter [48] Rb Ni Rb 2 [Ni(H 2 O) 6](SO 4) 2: Rubidium Nickel Sulfate Hexahydrate 6.221 12.41 9.131 106.055° 677.43 001 surface has step growth of 4.6 Å, optical transmission bands at 250, 500 and 860 nm which are the same as nickel sulfate hexahydrate, but UV band transmits more.
Nickel(II) sulfate is produced in large amounts by dissolving nickel metal or oxides in sulfuric acid, forming both a hexa- and heptahydrate [46] useful for electroplating nickel. Common salts of nickel, such as chloride, nitrate, and sulfate, dissolve in water to give green solutions of the metal aquo complex [Ni(H 2 O) 6] 2+. [47]
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Other double trichlorides include potassium nickel trichloride KNiCl 3 ·5H 2 O, [62] yellow cesium nickel trichloride CsNiCl 3, [62] lithium nickel trichloride LiNiCl 3 ·3H 2 O, [62] hyrdrazinium nickel tetrachloride, [62] and nickel ammonium chloride hexahydrate NH 4 NiCl 3 ·6H 2 O. [63] The tetrachloronickelates contain a tetrahedral NiCl ...
Unit activity for each solvent and pure solid or liquid species; and; Absolute partial pressure 101.325 kPa (1.00000 atm; 1.01325 bar) for each gaseous reagent — the convention in most literature data but not the current standard state (100 kPa). Variations from these ideal conditions affect measured voltage via the Nernst equation.