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Germanium tetrafluoride is a noncombustible, strongly fuming gas with a garlic-like odor. It reacts with water to form hydrofluoric acid and germanium dioxide. Decomposition occurs above 1000 °C. [5] Reaction of GeF 4 with fluoride sources produces GeF 5 − anions with octahedral coordination around Ge atom due to polymerization. [6]
Germanium tetrafluoride, GeF 4, a colorless molecular gas Index of chemical compounds with the same name This set index article lists chemical compounds articles associated with the same name.
It was the first discovered binary compound of a noble gas. [3] It is produced by the chemical reaction of xenon with fluorine: [4] [5] Xe + 2 F 2 → XeF 4. This reaction is exothermic, releasing an energy of 251 kJ/mol. [3] Xenon tetrafluoride is a colorless crystalline solid that sublimes at 117 °C.
Lewis structure of a water molecule. Lewis structures – also called Lewis dot formulas, Lewis dot structures, electron dot structures, or Lewis electron dot structures (LEDs) – are diagrams that show the bonding between atoms of a molecule, as well as the lone pairs of electrons that may exist in the molecule.
A notable derivative of GeCl 4 is germanium dioxide.In the manufacture of optical fibers, silicon tetrachloride, SiCl 4, and germanium tetrachloride, GeCl 4, are introduced with oxygen into a hollow glass preform, which is carefully heated to allow for oxidation of the reagents to their respective oxides and formation of a glass mixture.
Germanium difluoride forms orthorhombic crystals with a space group P2 1 2 1 2 1 (No. 19), Pearson symbol oP12, and lattice constants a = 0.4682 nm, b = 0.5178 nm, c = 0.8312 nm, Z = 4 (four structure units per unit cell). Its crystal structure is characterized by strong polymeric chains composed by GeF 3 pyramids.
Diboron tetrafluoride, B 2 F 4, a colorless gas; Dinitrogen tetrafluoride, N 2 F 4 (Tetrafluorohydrazine) Einsteinium tetrafluoride, EsF 4; Germanium tetrafluoride, GeF 4; Hafnium tetrafluoride, HfF 4; Iridium tetrafluoride, IrF 4; Iron tetrafluoride, FeF 4; Krypton tetrafluoride, KrF 4 (predicted) Lead tetrafluoride, PbF 4; Manganese ...
Two oxides of germanium are known: germanium dioxide (GeO 2, germania) and germanium monoxide, (GeO). [4] The dioxide, GeO 2 can be obtained by roasting germanium disulfide (GeS 2) or by allowing elemental germanium to slowly oxidze in air, [5] and is a white powder that is only slightly soluble in water but reacts with alkalis to form germanates. [4]