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  2. VSEPR theory - Wikipedia

    en.wikipedia.org/wiki/VSEPR_theory

    The bond angle for water is 104.5°. Valence shell electron pair repulsion (VSEPR) theory (/ ˈ v ɛ s p ər, v ə ˈ s ɛ p ər / VESP-ər, [1]: 410 və-SEP-ər [2]) is a model used in chemistry to predict the geometry of individual molecules from the number of electron pairs surrounding their central atoms. [3]

  3. Trigonal pyramidal molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Trigonal_pyramidal...

    3, and the sulfite ion, SO 2− 3. In organic chemistry, molecules which have a trigonal pyramidal geometry are sometimes described as sp 3 hybridized. The AXE method for VSEPR theory states that the classification is AX 3 E 1. Phosphine, an example of a molecule with a trigonal pyramidal geometry.

  4. Silicon tetrachloride - Wikipedia

    en.wikipedia.org/wiki/Silicon_tetrachloride

    Si + 2 Cl 2SiCl 4. It was first prepared by Jöns Jakob Berzelius in 1823. [4] Brine can be contaminated with silica when the production of chlorine is a byproduct of a metal refining process from metal chloride ore. In rare occurrences, the silicon dioxide in silica is converted to silicon tetrachloride when the contaminated brine is ...

  5. Seesaw molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Seesaw_molecular_geometry

    The seesaw geometry occurs when a molecule has a steric number of 5, with the central atom being bonded to 4 other atoms and 1 lone pair (AX 4 E 1 in AXE notation). An atom bonded to 5 other atoms (and no lone pairs) forms a trigonal bipyramid with two axial and three equatorial positions, but in the seesaw geometry one of the atoms is replaced ...

  6. Silane - Wikipedia

    en.wikipedia.org/wiki/Silane

    4 HCl + Mg 2 Si → SiH 4 + 2 MgCl 2 In general, the alkaline-earth metals form silicides with the following stoichiometries : M II 2 Si , M II Si , and M II Si 2 . In all cases, these substances react with Brønsted–Lowry acids to produce some type of hydride of silicon that is dependent on the Si anion connectivity in the silicide.

  7. Square pyramidal molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Square_pyramidal_molecular...

    The geometry is common for certain main group compounds that have a stereochemically-active lone pair, as described by VSEPR theory. Certain compounds crystallize in both the trigonal bipyramidal and the square pyramidal structures, notably [Ni(CN) 5] 3−. [1]

  8. Bent's rule - Wikipedia

    en.wikipedia.org/wiki/Bent's_rule

    According to VSEPR theory, diethyl ether, methanol, water and oxygen difluoride should all have a bond angle of 109.5 o. [12] Using VSEPR theory, all these molecules should have the same bond angle because they have the same "bent" shape. [12] Yet, clearly the bond angles between all these molecules deviate from their ideal geometries in ...

  9. Trichlorosilane - Wikipedia

    en.wikipedia.org/wiki/Trichlorosilane

    Si + 3 HCl → HCl 3 Si + H 2. Yields of 80-90% can be achieved. The main byproducts are silicon tetrachloride (chemical formula SiCl 4), hexachlorodisilane (Si 2 Cl 6) and dichlorosilane (H 2 SiCl 2), from which trichlorosilane can be separated by distillation. Tank car of trichlorosilane. UN number: 2988 (Chlorosilanes).