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Acetonitrile, often abbreviated MeCN (methyl cyanide), is the chemical compound with the formula CH 3 CN and structure H 3 C−C≡N. This colourless liquid is the simplest organic nitrile (hydrogen cyanide is a simpler nitrile, but the cyanide anion is not classed as organic). It is produced mainly as a byproduct of acrylonitrile manufacture.
[Cu(MeCN) 4] +, often encountered as its PF 6 − salt, is a common transition metal nitrile complex. Transition metal nitrile complexes are coordination compounds containing nitrile ligands. Because nitriles are weakly basic, the nitrile ligands in these complexes are often labile .
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The cation was first reported in 1923 with a nitrate anion as a byproduct of the reduction of silver nitrate with a suspension of copper powder in acetonitrile. [4] [ Cu(CH 3 CN) 4]PF 6 is generally produced by the addition of HPF 6 to a suspension of copper(I) oxide in acetonitrile: [5]
Chemical formula Name CAS number CH 3 CHO: acetaldehyde: 75-07-0 CH 3 CO 2 H: acetic acid: 64-19-7 (CH 3) 2 CO: acetone: 67-64-1 CH 3 CN: acetonitrile: 75-05-8 CH 3 CH 2 CH(OH)CH 2 OH: 1,2-Butanediol: 584-03-2
In chemistry, solvent effects are the influence of a solvent on chemical reactivity or molecular associations. Solvents can have an effect on solubility , stability and reaction rates and choosing the appropriate solvent allows for thermodynamic and kinetic control over a chemical reaction.
Solvent Density (g cm-3) Boiling point (°C) K b (°C⋅kg/mol) Freezing point (°C) K f (°C⋅kg/mol) Data source; Aniline: 184.3 3.69 –5.96 –5.87 K b & K f [1 ...
For parts that are inaccessible for lubrication after assembly, a dry film lubricant can be sprayed. After the solvent evaporates, the coating cures at room temperature to form a solid lubricant. Pastes are grease-like lubricants containing a high percentage of solid lubricants used for assembly and lubrication of highly loaded, slow-moving parts.